61214-26-4Relevant articles and documents
Bond Fixation in Annulenes. 8. Assessment of the Ring Inversion and Bond Shifting Barriers in 1,2,3-trimethylcyclooctatetraene. Resolution, Absolute Configuration and Circular Dichroism Behavior of an Annulene Hydrocarbon
Paquette, Leo A.,Gardlik, John M.
, p. 5016 - 5025 (2007/10/02)
A synthesis of racemic 1,2,3-trimethylcyclooctatetraene (13) based upon the expectation that 1,7,8-trimethylbicycloocta-2,4,7-triene (12) would open disrotatorily under orbital symmetry control was realized.This annulene demonstrated a ready pro