61350-01-4Relevant articles and documents
Copper-catalyzed: Ortho -C(sp2)-H amination of benzamides and picolinamides with alkylamines using oxygen as a green oxidant
Chen, Gong,Huang, Jie,Li, Qiong,Wang, Shui-Bo
, p. 4802 - 4814 (2020/07/13)
A versatile Cu-catalyzed direct ortho-C(sp2)-H amination of benzamides and picolinamides with alkylamines has been achieved. This method employs cheap and eco-friendly copper as a catalyst and oxygen as an oxidant, and also has the advantages of straightf
A N - (2 - morpholinyl -5 - trifluoromethyl phenyl) -2 - (3 - methylphenoxy) propionamide preparation method (by machine translation)
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Paragraph 0035; 0036; 0037; 0038, (2019/05/15)
The invention discloses a N - (2 - morpholinyl - 5 - trifluoromethyl-phenyl) - 2 - (3 - methylphenoxy) propionamide of the preparation method, comprises the following steps: The invention provides N - (2 - morpholinyl - 5 - trifluoromethyl-phenyl) - 2 -
Copper-catalyzed carboxamide-directed ortho amination of anilines with alkylamines at room temperature
Li, Qiong,Zhang, Shu-Yu,He, Gang,Ai, Zhaoyan,Nack, William A.,Chen, Gong
supporting information, p. 1764 - 1767 (2014/04/17)
In this report, a highly efficient method for the room temperature installation of alkyl amino motifs onto the ortho position of anilines via Cu-catalyzed carboxamide-directed amination with alkylamines is described. This method offers a practical solution for the rapid synthesis of complex arylamines from simple starting materials and enables new planning strategies for the construction of arylamine-containing pharmacophores. A single electron transfer (SET)-mediated mechanism is proposed.