6141-78-2Relevant articles and documents
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Arceneaux et al.
, p. 1419 (1959)
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SYNTHETIC, N.M.R. SPECTROSCOPIC AND X-RAY CRYSTALLOGRAPHIC INVESTIGATIONS ON THE PRODUCTS OF THE REACTIONS OF PHENYL (METHYL) PHOSPHONOTHIOIC DICHLORIDE AND THIOPHOSPHORYL CHLORIDE AND PSCl3 WITH PRIMARY AMINES
Hursthouse, Michael B.,Ibrahim, Ezzeldine H.,Parkes, Harold G.,Shaw, Leyla S.,Shaw, Robert A.,Watkins, David A.
, p. 261 - 266 (2007/10/02)
The syntheses in solution of (i) 2,4-dialkylamino-, (ii) 2,4-dimethyl-, and (iii) 2,4-diphenyl-2,4-dithio-cyclodiphosph(V)azanes, 2 (R' = NHR, Ph, or Me; R = alkyl), derived from thiophosphoryl trichloride, methylphosphonothioic and phenylphosphonothioic dichlorides and primary akylamines are described.N.m.r. spectroscopic properties for these cyclodiphosph(V)azanes and their monomeric precursors, R'P(S)(NHR)2 (R' = NHR, Ph, or Me; R = alkyl), are presented and structural inferences are drawn from this data.The X-ray crystal structure of i>2 is reported.
