61499-22-7

Basic information

• Product Name: 3-(4-ACETOXYPHENYL)-1-PROPENE
• Synonyms: ACETIC ACID 4-ALLYL-PHENYL ESTER;3-(4-ACETOXYPHENYL)-1-PROPENE
• CAS NO: 61499-22-7
• Molecular Formula: C₁₁H₁₂O₂
• Molecular Weight: 176.21
• Mol File: 61499-22-7.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 251.9°C at 760 mmHg
• Flash Point: 95.8°C
• Appearance: /
• Density: 1.027g/cm³
• Vapor Pressure: 0.02mmHg at 25°C
• Refractive Index: 1.512
• CAS DataBase Reference: 3-(4-ACETOXYPHENYL)-1-PROPENE(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(4-ACETOXYPHENYL)-1-PROPENE(61499-22-7)
• EPA Substance Registry System: 3-(4-ACETOXYPHENYL)-1-PROPENE(61499-22-7)

Safety Data

• Hazardous Substances Data: 61499-22-7(Hazardous Substances Data)

Usage

General Description

3-(4-acetoxypheynyl)-1-propene, also known as 4-acetoxy-alpha-methylstyrene, is a chemical compound with the molecular formula C11H12O2. 3-(4-ACETOXYPHENYL)-1-PROPENE is a derivative of phenylpropene and is typically used in the synthesis of organic compounds. It is a pale yellow liquid with a sweet floral odor and is insoluble in water but soluble in organic solvents. The primary use of 3-(4-acetoxypheynyl)-1-propene is as an intermediate in the production of other chemical compounds, such as pharmaceuticals and flavoring agents. However, it is important to handle this chemical with caution as it is a flammable substance and may cause irritation if it comes into contact with the skin or eyes.

InChI:InChI=1/C11H12O2/c1-3-4-10-5-7-11(8-6-10)13-9(2)12/h3,5-8H,1,4H2,2H3

Upstream product

• 140-67-0 Estragole 
• 108-24-7 acetic anhydride 
• 501-92-8 4-(prop-2-enyl)phenol 
• 106-41-2 4-bromo-phenol 
• 1927-95-3 4-bromophenyl acetate 
• 72824-04-5 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 

Downstream Products

• 175400-09-6 4-(2-fluoro-3-iodopropyl)phenyl acetate 
• 893403-73-1 4-(2,3-dinitrooxypropyl)phenyl acetate 
• 22805-47-6 3-(p-hydroxyphenyl)-1,2-propanediol 
• 175399-94-7 4-(2-fluoroprop-2-enyl)phenyl acetate 
• 670225-79-3 4-(2,3-epoxy-2-fluoropropyl)phenyl acetate 
• 58505-83-2 4‐((E)-2-formylvinyl)phenyl acetate 
• 2538-87-6 trans-p-hydroxycinnamaldehyde 

Relevant articles and documents

DDQ-mediated oxidation of allylarenes: Expedient access to cinnamaldehyde-containing phenylpropanoids

Phenylpropanoid natural products containing a cinnamaldehyde motif were easily synthesized from allylarenes mediated by 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) oxidation. Representative examples described herein are five types of 4-hydroxycinnamaldehyde derivatives from monolignols biosynthesis, Boropinal C, and 7-methoxywutaifuranal from plant extracts. Especially, simple synthesis of 7-methoxywutaifuranal was exploited through selective mono-oxidation and subsequent isomerization-ring-closing-metathesis strategy.

The synthesis of phenolic propane-1, 2- and 1,3-diols as intermediates in immobilised chelatants for the borate anion

The isomeric 3-(hydroxyphenyl)propane-1, 2-diols have been synthesised from allylic precursors by epoxidation and cleavage. Several different methods have been examined for obtaining 1-(methoxyphenyl)propane-1, 3-diols. 2-(methoxyphenyl)propane-1, 3-diols and certain hydroxy analogues have been obtained from benzaldoximes converted by oxidation to methoxy- and benzyloxynitromethylbenzenes followed by hydroxymethylation with formaldehyde and catalytic hydrogenation.

FeCl3-adsorbed on montmorillonite K-10: An efficient catalyst for one-pot dealkylation-acetylation of ethers

Direct conversion of ethers into acetates is achieved by treatment of ethers with acetic anhydride in the presence of FeCl3-adsorbed on montmorillonite K-10.