6161-50-8

Basic information

• Product Name: 3,3'-BIANISOLE
• Synonyms: 3,3'-BIANISOLE;3,3'-DIMETHOXYBIPHENYL;3,3'-Dimethoxy-1,1'-biphenyl;Biphenyl, 3,3'-dimethoxy-;3 3-DIMETHOXYBIPHENYL 97%;3 3-BIANISOLE 97%;Einecs 228-187-6;3,3′-Dimethoxybiphenyl,3,3′-Bianisole
• CAS NO: 6161-50-8
• Molecular Formula: C₁₄H₁₄O₂
• Molecular Weight: 214.26
• EINECS: 228-187-6
• Mol File: 6161-50-8.mol
• Article Data: 174

Chemical Properties

• Melting Point: 44-45 °C(lit.)
• Boiling Point: 328 °C(lit.)
• Flash Point: >230 °F
• Appearance: /
• Density: 1.0781 (rough estimate)
• Refractive Index: 1.5570 (estimate)
• CAS DataBase Reference: 3,3'-BIANISOLE(CAS DataBase Reference)
• NIST Chemistry Reference: 3,3'-BIANISOLE(6161-50-8)
• EPA Substance Registry System: 3,3'-BIANISOLE(6161-50-8)

Safety Data

• WGK Germany: 3
• HazardClass: IRRITANT
• Hazardous Substances Data: 6161-50-8(Hazardous Substances Data)

Usage

Uses

3,3''-Dimethoxy-1,1''-biphenyl is a useful reactant in organic synthesis.

Upstream product

• 766-85-8 3-methoxy-1-iodobenzene 
• 119-90-4 3,3'-dimethoxy-(1,1'-biphenyl)-4,4'-diamine 
• 36282-40-3 (3-methoxyphenyl)magnesium bromide 
• 612-76-0 1,1'-biphenyl-3,3'-diol 
• 77-78-1 dimethyl sulfate 
• 2398-37-0 3-methoxyphenyl bromide 
• 186581-53-3 diazomethane 
• 67-56-1 methanol 
• 138869-16-6 Bis (3-methoxyphenyl) methylphosphonate 
• 352-33-0 1-Chloro-4-fluorobenzene 
• 2845-89-8 1-chloro-3-methoxy-benzene 
• 14774-77-7 p-methoxyphenyllithium 
• 31600-88-1 m-methoxyphenyllithium 
• 6699-93-0 (2-methylphenyl)lithium 

Downstream Products

• 622011-31-8 9-(3',5-dimethoxy-[1,1'-biphenyl]-2-yl)-3,6-dimethoxy-9H-fluoren-9-ol 
• 4499-73-4 1³,2³,3²,4³-tetramethoxy-p-quarterphenyl 
• 195737-43-0 [1,4';1',1'';4'',1''']Quaterphenyl-3,2',2'',3'''-tetraol 
• 195737-42-9 1⁴,4⁴-diiodo-1³,2³,3²,4³-tetramethoxy-p-quarterphenyl 
• 195737-46-3 C₄₈H₅₈O₁₂ 
• 195737-47-4 C₇₂H₈₆O₁₈ 
• 195737-40-7 C₅₆H₅₀O₈ 
• 195737-44-1 [1,4';1',1'';4'',4''';1''',1'''';4'''',1''''']Sexiphenyl-3,2',2'',2''',2'''',3'''''-hexaol 
• 195737-39-4 3,2',2'',2''',2'''',3'''''-Hexamethoxy-[1,4';1',1'';4'',4''';1''',1'''';4'''',1''''']sexiphenyl 
• 34938-20-0 2,8-dimethoxyl-5-phenyldibenzophosphole 
• 55689-54-8 2,8-dimethoxy-5-phenyldibenzophosphole 5-oxide 

Relevant articles and documents

Visible Light Induced Aerobic Coupling of Arylboronic Acids Promoted by Hydrazone

A visible-light-induced oxidative coupling of arylboronic acids has been developed for the synthesis of biaryls. The reaction that employs polydentate hydrazones as the bifunctional catalyst works smoothly under room temperature. It is compatible with a w

Tandem Mn–I Exchange and Homocoupling Processes Mediated by a Synergistically Operative Lithium Manganate

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Pd-catalyzed cross-electrophile Coupling/C-H alkylation reaction enabled by a mediator generatedviaC(sp3)-H activation

Transition-metal-catalyzed cross-electrophile C(sp2)-(sp3) coupling and C-H alkylation reactions represent two efficient methods for the incorporation of an alkyl group into aromatic rings. Herein, we report a Pd-catalyzed cascade cross-electrophile coupling and C-H alkylation reaction of 2-iodo-alkoxylarenes with alkyl chlorides. Methoxy and benzyloxy groups, which are ubiquitous functional groups and common protecting groups, were utilized as crucial mediatorsviaprimary or secondary C(sp3)-H activation. The reaction provides an innovative and convenient access for the synthesis of alkylated phenol derivatives, which are widely found in bioactive compounds and organic functional materials.