61781-59-7Relevant articles and documents
Benzopyrones. Part 17. The Synthesis of some Bischromones and the Reaction of Cyanomethyl Esters with Sodium Azide
Bevan, Peter S.,Ellis, Gwynn P.,Wilson, H. Kerr
, p. 2552 - 2556 (1981)
Treatment of 4-oxochromen-2-carboxyl chloride with dimethylcadmium gave 1-methyl-1-(4-oxochromen-2-yl)ethyl 4-oxochromen-2-carboxylate (11) which was synthesized unequivocally and degraded to the carboxylic acid and 2-(1-methylvinyl)chromen-4-one. 2-Acetylchromen-4-one was synthesized by a new and more efficient method from 4-oxochromen-2-carbonyl chloride.The synthesis and some reactions of 4-oxochromen-2-yl isocyanate, and the cyanomethyl esters of 4-oxochromen-2-carboxylic and -2,6-dicarboxylic acids are descibed.