61794-43-2

Basic information

• Product Name: Benzene, 1,2,4,5-tetrafluoro-3-iodo-6-(trifluoromethyl)-
• Synonyms: 4-iodoheptafluorotoluene;Benzene,1,2,4,5-tetrafluoro-3-iodo-6-(trifluoromethyl);iodo-2,3,5,6-tetrafluoro-4-trifluoromethyl-benzene;4-Jodheptafluortoluol
• CAS NO: 61794-43-2
• Molecular Formula: C7F7I
• Molecular Weight: 343.97
• Mol File: 61794-43-2.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Benzene, 1,2,4,5-tetrafluoro-3-iodo-6-(trifluoromethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,2,4,5-tetrafluoro-3-iodo-6-(trifluoromethyl)-(61794-43-2)
• EPA Substance Registry System: Benzene, 1,2,4,5-tetrafluoro-3-iodo-6-(trifluoromethyl)-(61794-43-2)

Safety Data

• Hazardous Substances Data: 61794-43-2(Hazardous Substances Data)

Upstream product

• 591-50-4 iodobenzene 
• 1227710-53-3 [bis(trifluoroacetoxy)iodo]-2,3,5,6-tetrafluoro-4-trifluoromethyl-benzene 
• 1868-85-5 (2,3,5,6-tetrafluoro-4-(trifluoromethyl)phenyl)hydrazine 
• 651-80-9 1,2,4,5-tetrafluoro-3-(trifluoromethyl)benzene 

Downstream Products

• 1227710-53-3 [bis(trifluoroacetoxy)iodo]-2,3,5,6-tetrafluoro-4-trifluoromethyl-benzene 
• 4526-07-2 1,4-bis(trimethylsilyl)-1,3-butadiyne 
• 1315381-38-4 C₃₂F₂₂ 
• 137832-25-8 tribromogermylheptafluoro-4-methylbenzene 
• 61794-55-6 1.4-Bis-(4'-trifluormethyltetrafluorphenyl)butadiin 
• 61794-56-7 4-Trifluormethyltetrafluorphenylacetylen 
• 122571-42-0 trimethyl(2,3,5,6-tetrafluoro-4-(trifluoromethyl)phenyl)silane 
• 61794-47-6 1-(4-trifluoromethyl-2,3,5,6-tetrafluorophenyl)-1-propyn-3-ol 

Relevant articles and documents

A versatile and highly reactive polyfluorinated hypervalent iodine (III) compound

(Figure Presented) Hyper-reactive: A highly reactive, fully fluorinated hypervalent iodine reagent (see formula) mediates new transformations (e.g. the one-pot conversion of sulfides to sulfoximines) and serves as a stoichiometric oxidant in well-established reactions (e.g. C-C bond cleavage and the conversion of alcohols into aldehydes).

REACTIONS OF POLYFLUOROARYL BROMIDES AND IODIDES WITH C-, Si-, Ge-, Sn- AND Pb-ELECTROPHILES AND TRIS(DIALKYLAMINO)PHOSPHINES

The reactions of polyfluoroaryl bromides ArFBr or iodides ArFI with P(NR'2)3 and R3MX (R = alkyl; M = Si, Ge, Sn and Pb; X = Cl, Br) led to the formation of ArFMR3.The reactions of C6F5Br with P(NEt2)3 and C-electrophiles (CH3I, C6F5CF3 and (CF3)2C=CFC2F5) gave the products of pentafluorophenylation of these substrates.