62013-44-9

Basic information

• Product Name: methyl 2-nitro-propionate
• CAS NO: 62013-44-9
• Molecular Weight: 133.104
• Mol File: 62013-44-9.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: methyl 2-nitro-propionate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2-nitro-propionate(62013-44-9)
• EPA Substance Registry System: methyl 2-nitro-propionate(62013-44-9)

Safety Data

• Hazardous Substances Data: 62013-44-9(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 79-24-3 Nitroethane 
• 124-38-9 carbon dioxide 
• 2483-57-0 methyl 2-nitroacetate 
• 74-88-4 methyl iodide 
• 61985-23-7 methyl 1-imidazolecarboxylate 
• 79-22-1 methyl chloroformate 
• 65397-15-1 sodium methoxycarbonylmethane nitronate 
• 5445-17-0 Methyl 2-bromopropionate 

Downstream Products

• 7625-53-8 rac-Ala-OMe 
• 56145-24-5 methyl 2-methyl-5-oxopyrrolidine-2-carboxylate 
• 113747-75-4 methyl 2-methyl-2-nitro-1,5-pentanedicarboxylate 
• 1088705-78-5 C₁₇H₂₄N₂O₆ 
• 1088705-70-7 C₁₆H₂₁FN₂O₆ 
• 1088705-74-1 C₁₆H₂₁ClN₂O₆ 
• 1088705-72-9 C₁₆H₂₁ClN₂O₆ 
• 1088705-68-3 C₁₆H₂₂N₂O₆ 
• 1088705-76-3 C₁₇H₂₄N₂O₆ 
• 1430818-89-5 methyl (2S,3S)-3-((diethoxyphosphoryl)amino)-3-(4-fluorophenyl)-2-methyl-2-nitropropanoate 
• 1430818-90-8 methyl (2S,3S)-3-((diethoxyphosphoryl)amino)-3-(4-chlorophenyl)-2-methyl-2-nitropropanoate 
• 1430818-91-9 methyl (2S,3S)-3-((diethoxyphosphoryl)amino)-3-(4-bromophenyl)-2-methyl-2-nitropropanoate 
• 1430818-92-0 methyl (2S,3S)-3-((diethoxyphosphoryl)amino)-2-methyl-2-nitro-3-(p-tolyl)propanoate 
• 1430818-93-1 methyl (2S,3S)-3-((diethoxyphosphoryl)amino)-2-methyl-2-nitro-3-(m-tolyl)propanoate 

Relevant articles and documents

Inclusion complexes of EMPO derivatives with 2,6-di-O-methyl-β- cyclodextrin: Synthesis, NMR and EPR investigations for enhanced superoxide detection

The free radical trapping properties of eight 5-alkoxycarbonyl-5-methyl-1- pyrroline N-oxide (EMPO) type nitrones and those of 5,5-dimethyl-1-pyrroline N-oxide (DMPO) were evaluated for trapping of superoxide anion radicals in the presence of 2,6-di-O-methyl-β-cyclodextrin (DM-β-CD). 1H-NMR titrations were performed to determine both stoichiometries and binding constants for the diamagnetic nitrone-DM-β-CD equilibria. EPR titrations were then performed and analyzed using a two-dimensional EPR simulation program affording 1: 1 and 1: 2 stoichiometries for the nitroxide spin adducts with DM-β-CD and the associated binding constants after spin trapping. The nitroxide spin adducts associate more strongly with DM-β-CD than the nitrones. The ability of the nitrones to trap superoxide, the enhancement of the EPR signal intensity and the supramolecular protection by DM-β-CD against sodium l-ascorbate reduction were evaluated. The Royal Society of Chemistry 2006.

CARBON-CARBON BOND FORMATION BY MEANS OF SUBSTITUTION AND ADDITION REACTIONS INVOLVING THE POLYMER-SUPPORTED CARBANION FROM METHYL NITROACETATE

A polymer-supported carbanion has been prepared from methyl nitroacetate and reacted with alkyl halides or activated olefins to give α-nitroesters.