62054-77-7

Basic information

• Product Name: methyl 3-(2,2-dimethyl-4,6-dioxo-1,3-dioxan-5-yl)propanoate
• Synonyms: methyl 3-(2,2-dimethyl-4,6-dioxo-1,3-dioxan-5-yl)propanoate
• CAS NO: 62054-77-7
• Molecular Formula: C₁₀H₁₄O₆
• Molecular Weight: 230.21456
• EINECS: -0
• Mol File: 62054-77-7.mol
• Article Data: 2

Chemical Properties

• Melting Point: 78.0-79.5 °C
• Boiling Point: 408.7±30.0 °C(Predicted)
• Appearance: /
• Density: 1.186±0.06 g/cm3(Predicted)
• PKA: 12.16±0.40(Predicted)
• CAS DataBase Reference: methyl 3-(2,2-dimethyl-4,6-dioxo-1,3-dioxan-5-yl)propanoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 3-(2,2-dimethyl-4,6-dioxo-1,3-dioxan-5-yl)propanoate(62054-77-7)
• EPA Substance Registry System: methyl 3-(2,2-dimethyl-4,6-dioxo-1,3-dioxan-5-yl)propanoate(62054-77-7)

Safety Data

• Hazardous Substances Data: 62054-77-7(Hazardous Substances Data)

Upstream product

• 2033-24-1 cycl-isopropylidene malonate 
• 292638-85-8 acrylic acid methyl ester 

Downstream Products

• 5621-44-3 dimethyl 2-methylenepentanedioate 

Relevant articles and documents

A new method for constructing quaternary carbon centres: Tandem rhodium-catalysed 1,4-addition/intramolecular cyclisation

The efficient tandem rhodium-catalysed 1,4-addition/cyclisation of 1,1′-alkenes using arylzinc chlorides is described. The simple one-step synthesis of substituted cyclopentanone and cyclohexanone derivatives is performed from acyclic precursors using relatively low catalyst loadings under mild conditions. A new quaternary carbon centre is created during the cyclisation step.