622815-22-9Relevant articles and documents
Rapid entry into heterocycle-fused benzylic azepines and azocines via directed metallation/ring-closing metathesis
Moss, Thomas A.
, p. 4254 - 4258 (2013)
The efficient synthesis of a range of heterocycle-fused benzylic azepine and azocine derivatives is reported, employing a directed metallation/ruthenium- catalysed ring-closing metathesis approach. A base-mediated tautomerisation approach can be used to access both the azepine and azocine derivatives from the same starting material.