62311-60-8

Basic information

• Product Name: N-<(1R^*,5R^*)-carvyl>benzamide
• CAS NO: 62311-60-8
• Molecular Weight: 255.36
• Mol File: 62311-60-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-<(1R^*,5R^*)-carvyl>benzamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-<(1R^*,5R^*)-carvyl>benzamide(62311-60-8)
• EPA Substance Registry System: N-<(1R^*,5R^*)-carvyl>benzamide(62311-60-8)

Safety Data

• Hazardous Substances Data: 62311-60-8(Hazardous Substances Data)

Upstream product

• 7111-29-7 (1R-cis)-2-methyl-5-(1-methylethenyl)-2-cyclohexen-1-ol acetate 
• 98-88-4 benzoyl chloride 
• 53567-64-9 (1R^*,5R^*)-p-1,8-menthadien-6-ylamine 
• 2051-55-0 (S)-p-mentha-6,8-dien-2-one-(Z)-oxime 
• 65877-16-9 (R)-p-mentha-6,8-dien-2-one-(Z)-oxime 
• 53567-64-9 carvylamine 

Relevant articles and documents

Palladium(0)-Catalyzed Azidation of Allyl Esters. Selective Synthesis of Allyl Azides, Primary Allylamines, and Related Compounds

Palladium(0)-catalyzed reaction of allyl esters such as phosphates, carbonates, and carboxylates with sodium azide gives allyl azides.The azidation proceeds with retention of configuration at the allylic carbon.Optically active (R)-(E)-(+)-4-phenyl-3-buten-2-yl azide (19) is obtained from (R)-(E)-(+)-4-phenyl-3-buten-2-yl acetate (18) stereoselectively.Sequential substitution of (Z)-4-acetoxy-2-buten-1-yl diethyl phosphate (24) with nucleophiles and subsequently azide ion gives (E)-4-substituted-2-buten-1-yl azides 27.The reaction of allyl azides with triphenylphosphine gives iminotriphenylphosphoranes, which are versatile synthetic intermediates of primary allylamines, N-allylamines, and N-allylamides.Treatment of allyl azides with triphenylphosphine and subsequently with aqueous ammonium solution gives primary allylamines.Other synthetic applications of allyl azides are also described.