6235-14-9Relevant articles and documents
Study on comparison of reducing ability of three organic hydride compounds
Feng, Yi-Si,Yang, Chun-Yan,Huang, Qiang,Xu, Hua-Jian
experimental part, p. 5053 - 5059 (2012/07/28)
Selective reduction of three kinds of substrates were studied to evaluate the reducing abilities of N,N-dimethyl-benzimidazolidine (DMBI), 2-phenylbenzimidazoline (PBI) and 2-phenylbenzothiazoline (PBT). As hydride donors, these three five-membered heterocyclic compounds performed different reducing abilities depending on the substrates.
A study on the reactions of NADH models with electron-deficient alkenes. A probe for the extreme of concerted electron-hydrogen atom transfer mechanism
Fang, Xin-Qiang,Xu, Hua-Jian,Jiang, Hong,Liu, You-Cheng,Fu, Yao,Wu, Yun-Dong
scheme or table, p. 312 - 315 (2009/04/14)
The reactions of 9-fluorenylidenemalononitrile (FDCN) and 1,1-diphenyl-2,2-dicyanoethylene (DPCN) with Hantzsch ester (HEH), N-methyl Hantzsch ester (Me-HEH), and 1-benzyl-1,4-dihydronicotinamide (BNAH) in oxygen-saturated acetonitrile have been studied. The aerobic reactions with HEH give solely reduction products. However, reactions with Me-HEH and BNAH not only result in reduction products, but also give varying amounts of oxidation products. The amount of oxidation product appears to be related to the electronic character and bulkiness of reactants. We propose that all these reactions follow a general mechanism of concerted electron-hydrogen atom transfer mechanism. If the electron-transfer complex is very tight, only 'concerted hydride transfer reaction' occurs. However, if the electron-transfer complex is not so tight, oxygen can capture the radicaloid intermediate to result in oxidation products.
Carbanion: The First Example To Generate Thermodynamically Unfavorable 9-(Dicyanomethyl)fluorenide Anion
Zhu, Xiao-Qing,Liu, You-Cheng
, p. 2786 - 2787 (2007/10/03)
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