62351-49-9

Basic information

• Product Name: Benzaldehyde, 2-(methylsulfinyl)-
• CAS NO: 62351-49-9
• Molecular Formula: C8H8O2S
• Molecular Weight: 168.216
• Mol File: 62351-49-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzaldehyde, 2-(methylsulfinyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzaldehyde, 2-(methylsulfinyl)-(62351-49-9)
• EPA Substance Registry System: Benzaldehyde, 2-(methylsulfinyl)-(62351-49-9)

Safety Data

• Hazardous Substances Data: 62351-49-9(Hazardous Substances Data)

Upstream product

• 6630-33-7 ortho-bromobenzaldehyde 

Downstream Products

• 103785-58-6 4-(2-Methanesulfinyl-phenyl)-2,6-dimethyl-1,4-dihydro-pyridine-3,5-dicarboxylic acid 3-methyl ester 5-(2-methyl-[1,3]dioxolan-2-ylmethyl) ester 
• 99880-17-8 4-(2-Methanesulfinyl-phenyl)-2,6-dimethyl-1,4-dihydro-pyridine-3,5-dicarboxylic acid 3-methyl ester 5-(2-oxo-propyl) ester 
• 99880-26-9 4-(2-Methanesulfinyl-phenyl)-2,6-dimethyl-1,4-dihydro-pyridine-3,5-dicarboxylic acid 3-cyclopropylmethyl ester 5-methyl ester 
• 103785-50-8 methyl 2-(2-methylsulfinylphenylmethylene)acetoacetate 

Relevant articles and documents

Rhodium(III)-Catalyzed Aldehyde C?H Activation and Functionalization with Dioxazolones: An Entry to Imide Synthesis

A rhodium(III)-based catalytic system has been used to develop a C?H bond activation of benzaldehyde derivatives and subsequent functionalization with dioxazolones in order to afford imides. The importance of the nature of the directing group to perform selectively the aldehydic C?H bond activation has been highlighted. The scope investigation showed that this transformation could be applied to various dioxazolones and many benzaldehyde derivatives as well as an acrolein derivative. Derivatization reactions of the imide products demonstrated the synthetic utility of this rhodium-catalyzed aldehydic C?H amidation.