62557-94-2

Basic information

• Product Name: 1-Butanone, 3-(4-methoxyphenyl)-1-phenyl-
• CAS NO: 62557-94-2
• Molecular Formula: C17H18O2
• Molecular Weight: 254.329
• Mol File: 62557-94-2.mol
• Article Data: 12

Chemical Properties

• CAS DataBase Reference: 1-Butanone, 3-(4-methoxyphenyl)-1-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Butanone, 3-(4-methoxyphenyl)-1-phenyl-(62557-94-2)
• EPA Substance Registry System: 1-Butanone, 3-(4-methoxyphenyl)-1-phenyl-(62557-94-2)

Safety Data

• Hazardous Substances Data: 62557-94-2(Hazardous Substances Data)

Upstream product

• 3319-15-1 rac-1-(4-methoxyphenyl)-ethanol 
• 536-74-3 phenylacetylene 
• 13735-81-4 1-styrenyloxytrimethylsilane 
• 1515-95-3 p-ethylanisole 
• 123-11-5 4-methoxy-benzaldehyde 
• 108454-55-3 3-(4-methoxyphenyl)-2-butenoic acid ethyl ester 
• 1354197-48-0 (E)-3-(4-methoxyphenyl)-1-phenylbut-2-en-1-one 
• 5440-69-7 N-isopropylbenzamide 
• 1712-69-2 1-isopropenyl-4-methoxybenzene 
• 495-41-0 1-phenylbut-2-en-1-one 
• 5720-07-0 4-methoxyphenylboronic acid 
• 100-06-1 1-(4-methoxyphenyl)ethanone 
• 696-62-8 para-iodoanisole 
• 70-11-1 α-bromoacetophenone 

Relevant articles and documents

Arylboronic Acid Catalyzed C-Alkylation and Allylation Reactions Using Benzylic Alcohols

The arylboronic acid catalyzed dehydrative C-alkylation of 1,3-diketones and 1,3-ketoesters using secondary benzylic alcohols as the electrophile is reported, forming new C-C bonds (19 examples, up to 98% yield) with the release of water as the only byproduct. The process is also applicable to the allylation of benzylic alcohols using allyltrimethylsilane as the nucleophile (12 examples, up to 96% yield).

Ketone Synthesis by Direct, Orthogonal Chemoselective Hydroacylation of Alkenes with Amides: Use of Alkenes as Surrogates of Alkyl Carbanions

Direct functionalization of alkenes and direct transformation of carboxamides are two exciting areas that have attracted considerable attention in recent years. We report herein that secondary amides, the least reactive derivatives of carbonyl compounds, upon activated with triflic anhydride, can serve as effective hydroacylating reagents in partner with alkenes to yield ketones at ambient temperature. The method was applied to the one-step synthesis of racemic dihydro-ar-turmerone. In this method, alkenes serve as surrogates of organometallic reagents, which allows the orthogonal chemoselective reactions. The ready availability of many olefins such as camphene and norbornene permits one-step ketone synthesis that would require several steps by conventional methods.

Unprecedented alkylation of silicon enolates with alcohols via carbenium ion formations catalyzed by tin hydroxide-embedded montmorillonite

The solid acid, tin hydroxide-embedded montmorillonite, catalyzes the unprecedented alkylation of various silicon enolates with primary, secondary and tertiary benzylic alcohols as well as secondary allylic alcohols. The acid catalysis of Sn-Mont was not only higher than that of the other ion-exchanged montmorillonites (M-Mont; M?=?H, Ti, Fe and Al), but also higher than that of the typical homogeneous acid catalysts such as BF3·OEt2, TMSOTf and TfOH.