6256-06-0Relevant articles and documents
Cerium(IV) ammonium nitrate induced dimerization of methoxystyrenes
Nair, Vijay,Sheeba,Panicker, Sreeletha B.,George, Tesmol G.,Rajan, Roshini,Balagopal, Lakshmi,Vairamani,Prabhakar
, p. 2461 - 2467 (2007/10/03)
4-Methoxystyrene 1 underwent dimerization to 1,4-diphenylbutane derivatives 5 and 6 in presence of CAN in methanol. But in ethanol the same reaction afforded a tetralone derivative along with 5 and 6.3,4- Dimethoxystyrene 10 underwent dimerization in pres
Reactions of Aryl Cyclopropyl Ketones. A New Synthesis of Aryl Tetralones
Murphy, William S.,Wattanasin, Sompong
, p. 2920 - 2926 (2007/10/02)
Aryl cyclopropyl ketones (2) cyclise to 1-tetralones (3) in the presence of a variety of acid catalysts under mild conditions.Open-chain carbinols (4) are also formed.The ratio of (3) to (4) is dependent on the aryl ring substituents.A cationic mechanism is proposed.Cyclopropyl ketones (1) do not react.Stereoelectronic factors involved in the reactivity of the rigig cyclopropyl ketone (12) are discussed.The reactions of selected phenolic cyclopropyl ketones have been investigated as anionic counterparts to the acid-catalysed reactions.No reaction is observed.
Further experimental data on racemic galbuline and its structurally allied compounds
Traverso,Pollini
, p. 35 - 50 (2007/10/06)
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