6258-48-6Relevant articles and documents
Blue LED Irradiation of Iodonium Ylides Gives Diradical Intermediates for Efficient Metal-free Cyclopropanation with Alkenes
Chidley, Tristan,Jameel, Islam,Rizwan, Shafa,Peixoto, Philippe A.,Pouységu, Laurent,Quideau, Stéphane,Hopkins, W. Scott,Murphy, Graham K.
, p. 16959 - 16965 (2019/11/11)
A facile and highly chemoselective synthesis of doubly activated cyclopropanes is reported where mixtures of alkenes and β-dicarbonyl-derived iodonium ylides are irradiated with light from blue LEDs. This metal-free synthesis gives cyclopropanes in yields