626239-69-8Relevant articles and documents
Total synthesis of the coccinellid alkaloid (±)-adalinine utilizing a nitrenium ion cyclization
Wardrop, Duncan J.,Landrie, Chad L.,Ortíz, José A.
, p. 1352 - 1354 (2007/10/03)
The total synthesis of (±)-adalinine, a piperidine alkaloid from the European two-spotted ladybird Adalia bipunctata, is reported. Central to this undertaking are (i) the use of an N-alkoxy-N-acylnitrenium ion-induced spirocyclization to rapidly access th