62641-34-3

Basic information

• Product Name: Benzenamine, N-dodecyl-4-methyl-
• CAS NO: 62641-34-3
• Molecular Formula: C19H33N
• Molecular Weight: 275.478
• Mol File: 62641-34-3.mol
• Article Data: 13

Chemical Properties

• CAS DataBase Reference: Benzenamine, N-dodecyl-4-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, N-dodecyl-4-methyl-(62641-34-3)
• EPA Substance Registry System: Benzenamine, N-dodecyl-4-methyl-(62641-34-3)

Safety Data

• Hazardous Substances Data: 62641-34-3(Hazardous Substances Data)

Upstream product

• 765-03-7 1-dodecyne 
• 106-49-0 p-toluidine 
• 106-44-5 p-cresol 
• 124-22-1 n-Dodecylamine 
• 112-54-9 Dodecanal 
• 99-99-0 1-methyl-4-nitrobenzene 
• 143-07-7 lauric acid 
• 589-92-4 1-methylcyclohexan-4-one 
• 112-53-8 1-dodecyl alcohol 
• 106-43-4 para-chlorotoluene 
• 112-52-7 1-chlorododecane 
• 143-15-7 1-dodecylbromide 
• 624-31-7 4-tolyl iodide 

Downstream Products

• 1198092-13-5 N-allyl-N-dodecyl-4-methylbenzenamine 

Relevant articles and documents

Catalytic Amination of Phenols with Amines

Given the wide prevalence and ready availability of both phenols and amines, aniline synthesis through direct coupling between these starting materials would be extremely attractive. Herein, we describe a rhodium-catalyzed amination of phenols, which provides concise access to diverse anilines, with water as the sole byproduct. The arenophilic rhodium catalyst facilitates the inherently difficult keto–enol tautomerization of phenols by means of π-coordination, allowing for the subsequent dehydrative condensation with amines. We demonstrate the generality of this redox-neutral catalysis by carrying out reactions of a large array of phenols with various electronic properties and a wide variety of primary and secondary amines. Several examples of late-stage functionalization of structurally complex bioactive molecules, including pharmaceuticals, further illustrate the potential broad utility of the method.

Chelating Bis(1,2,3-triazol-5-ylidene) Rhodium Complexes: Versatile Catalysts for Hydrosilylation Reactions

NHC-rhodium complexes (NHC=N-heterocyclic carbenes) have been widely used as efficient catalysts for hydrosilylation reactions. However, the substrates were mostly limited to reactive carbonyl compounds (aldehydes and ketones) or carbon-carbon multiple bonds. Here, we describe the application of newly-developed chelating bis(tzNHC)-rhodium complexes (tz=1,2,3-triazol-5-ylidene) for several reductive transformations. With these catalysts, the formal reductive methylation of amines using carbon dioxide, the hydrosilylation of amides and carboxylic acids, and the reductive alkylation of amines using carboxylic acids have been achieved under mild reaction conditions.

Palladium-catalyzed aerobic dehydrogenative aromatization of cyclohexanone imines to arylamines

Dehydrogenative aromatization of cyclohexanone imines to arylamines has been achieved using a palladium catalyst under aerobic conditions. The reaction is applicable to a variety of imines that are either preformed or generated in situ from cyclohexanone derivatives and aryl or alkylamines.