62740-72-1

Basic information

• Product Name: Benzenemethanamine, a-butyl-N-phenyl-
• CAS NO: 62740-72-1
• Molecular Formula: C17H21N
• Molecular Weight: 239.36
• Mol File: 62740-72-1.mol
• Article Data: 16

Chemical Properties

• CAS DataBase Reference: Benzenemethanamine, a-butyl-N-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanamine, a-butyl-N-phenyl-(62740-72-1)
• EPA Substance Registry System: Benzenemethanamine, a-butyl-N-phenyl-(62740-72-1)

Safety Data

• Hazardous Substances Data: 62740-72-1(Hazardous Substances Data)

Upstream product

• 109-72-8 n-butyllithium 
• 136580-21-7 N-methoxydiphenyl methyl amine 
• 6846-55-5 ethyl 3-anilino-3-phenylpropanoate 
• 62-53-3 aniline 
• 1009-14-9 phenyl butyl ketone 
• 77821-54-6 Phenyl-[1-phenyl-pent-(Z)-ylidene]-amine 
• 5384-63-4 1,1-diphenylpentanol 
• 109-52-4 valeric acid 
• 624-24-8 methyl valerate 
• 2325-27-1 N-phenyltriphenyliminophosphorane 
• 622-37-7 Phenyl azide 
• 3376-32-7 benzaldehyde O-methyloxime 
• 591-51-5 phenyllithium 
• 109-69-3 n-Butyl chloride 

Relevant articles and documents

Iron-catalysed 1,2-aryl migration of tertiary azides

1,2-Aryl migration of α,α-diaryl tertiary azides was achieved by using the catalytic system of FeCl2/N-heterocyclic carbene (NHC) SIPr·HCl. The reaction generated aniline products in good yields after one-pot reduction of the migration-resultant imines.

Unprecedented Nucleophilic Additions of Highly Polar Organometallic Compounds to Imines and Nitriles Using Water as a Non-Innocent Reaction Medium

In contrast to classic methods carried out under inert atmospheres with dry volatile organic solvents and often low temperatures, the addition of highly polar organometallic compounds to non-activated imines and nitriles proceeds quickly, efficiently, and chemoselectively with a broad range of substrates at room temperature and under air with water as the only reaction medium. Secondary amines and tertiary carbinamines are furnished in yields of up to and over 99 %. The significant solvent D/H isotope effect observed for the on-water nucleophilic additions of organolithium compounds to imines suggests that the on-water catalysis arises from proton transfer across the organic–water interface. The strong intermolecular hydrogen bonds between water molecules may play a key role in disfavoring protonolysis, which occurs extensively in other protic media such as methanol. This work lays the foundation for reshaping many fundamental s-block metal-mediated organic transformations in water.

Development of highly enantioselective new Lewis basic N-formamide organocatalysts for hydrosilylation of imines with an unprecedented substrate profile

l-Pipecolinic acid derived N-formamides have been developed as new Lewis basic organocatalysts that promote the asymmetric reduction of N-aryl ketimines using trichlorosilane as the reducing agent. The substituent on N4 of the piperazinyl backbone and the