62747-73-3Relevant articles and documents
Rhodium-catalyzed synthesis of isoquinolines and indenes from benzylidenehydrazones and internal alkynes
Huang, Xiao-Cheng,Yang, Xu-Heng,Song, Ren-Jie,Li, Jin-Heng
, p. 1025 - 1031 (2014/03/21)
A new route is presented for the selective assembly of isoquinolines and indenes by rhodium-catalyzed tandem cyclization of benzylidenehydrazones with internal alkynes. This method involves the selective cleavage of the N-N bond and the C=N bonds and is dependent on the substituents of the benzylidenehydrazone.
One-pot synthetic routes to multiply substituted indene derivatives by hydrolysis of zirconocene-mediated intermolecular coupling reactions of aromatic ketones and alkynes
Xi, Zhenfeng,Guo, Ruiyun,Mito, Shizue,Yan, Hongliang,Kanno, Ken-ichiro,Nakajima, Kiyohiko,Takahashi, Tamotsu
, p. 1252 - 1257 (2007/10/03)
Two one-pot multicomponent synthetic methods for highly substituted indenes are described. The intermolecular coupling of aromatic ketones with alkynes on low-valent zirconocene species generates oxazirconacyclopentenes, which upon hydrolysis with 20% HCl
Sigmatropic Indenyl Rearrangements Induced by Electronic Excitation
Padwa, Albert,Goldstein, Steven,Loza, Roman,Pulwer, Mitchell
, p. 1858 - 1868 (2007/10/02)
The photochemical rearrangement of several arylalkyl substituted indenes has been studied.The rearrangements were shown to be derived from the ?,?* singlet state since triplet sensitization led to no reaction or else resulted in a Paterno-Buchi