627877-60-5Relevant articles and documents
Development of Chiral Nucleophilic Pyridine Catalysts: Applications in Asymmetric Quaternary Carbon Synthesis
Shaw, Scott A.,Aleman, Pedro,Vedejs, Edwin
, p. 13368 - 13369 (2007/10/03)
TADMAP (1a), a new chiral DMAP catalyst, has been designed to place a C(3)-benzylic trityl group over one face of the pyridine ring, while a C(3)-benzylic acetoxy group creates a chirotopic environment on the other face. TADMAP was prepared in four steps