627906-96-1

Basic information

• Product Name: 1,3,2-Dioxaborinane, 5,5-dimethyl-2-(2-naphthalenyl)-
• CAS NO: 627906-96-1
• Molecular Formula: C15H17BO2
• Molecular Weight: 240.11
• Mol File: 627906-96-1.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: 1,3,2-Dioxaborinane, 5,5-dimethyl-2-(2-naphthalenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3,2-Dioxaborinane, 5,5-dimethyl-2-(2-naphthalenyl)-(627906-96-1)
• EPA Substance Registry System: 1,3,2-Dioxaborinane, 5,5-dimethyl-2-(2-naphthalenyl)-(627906-96-1)

Safety Data

• Hazardous Substances Data: 627906-96-1(Hazardous Substances Data)

Usage

General Description

1,3,2-Dioxaborinane, 5,5-dimethyl-2-(2-naphthalenyl)-, also known as 5,5-Dimethyl-2-(2-naphthalenyl) dioxaborolane, is a chemical compound with the molecular formula C16H17BO2. It is a boron-containing heterocyclic compound that is used in organic synthesis and medicinal chemistry. 1,3,2-Dioxaborinane, 5,5-dimethyl-2-(2-naphthalenyl)- is commonly used as a building block in the synthesis of various organic compounds and pharmaceuticals. It is known for its stability and reactivity, making it a valuable tool in the field of chemical research and development. Additionally, 1,3,2-Dioxaborinane, 5,5-dimethyl-2-(2-naphthalenyl)- is also used as a ligand in transition metal-catalyzed cross-coupling reactions, making it an important component in the production of complex organic molecules.

Upstream product

• 201733-56-4 2-(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)-5,5-dimethyl-1,3,2-dioxaborinane 
• 24547-46-4 2-naphthalen-2-yloxy-pyrimidine 
• 93-04-9 2-Methoxynaphthalene 
• 613-62-7 2-benzyloxynaphthalene 
• 93-18-5 2-ethoxynaphthalene 
• 38348-86-6 1-(naphthalen-2-yl)pyrrolidin-2-one 
• 1503-86-2 2-naphthyl pivalate 
• 93-44-7 2-naphthyl benzoate 
• 1523-11-1 naphthalen-2-yl acetate 
• 115311-03-0 2-(tert-butoxycarbonyloxy)naphthalene 

Downstream Products

• 93-09-4 naphthalene-2-carboxylate 
• 827-54-3 2-naphthylethylene 
• 1188303-86-7 1-(3-fluorophenyl)-1-(naphthalen-2-yl)propan-1-ol 
• 1393793-79-7 2-(2-bromo-5-methoxyphenyl)naphthalene 
• 1393793-81-1 C₁₉⁽¹³⁾C₂H₂₀O₃ 
• 1393793-82-2 ethyl 2-(4-methoxy-2-(naphthalen-2-yl)phenyl)acetic acid 
• 1393793-83-3 C₁₇⁽¹³⁾C₂H₁₆O₃ 
• 1393794-09-6 C₁₆⁽¹³⁾C₂H₁₄O₂ 
• 1393794-07-4 ethyl 2-(2-naphthalenyl)phenylacetate 
• 1393794-08-5 C₁₈⁽¹³⁾C₂H₁₈O₂ 
• 50-32-8 benzopyrene 
• 205522-38-9 2-(2-naphthalenyl)phenylacetic acid 
• 17573-21-6 9-Hydroxybenzo[a]pyrene 
• 84498-34-0 chrysen-5-ol 

Relevant articles and documents

Nickel-Catalyzed Borylation of Aryl and Benzyl 2-Pyridyl Ethers: A Method for Converting a Robust ortho-Directing Group

The nickel-catalyzed borylation of aryl 2-pyridyl ethers via the loss of a 2-pyridyloxy group is described. This method allows a 2-pyridyloxy group to be used as a convertible directing group in C?H bond functionalization reactions. The nickel catalyst can also borylate arylmethyl 2-pyridyl ethers, in which the stereochemistry at the benzylic position is retained in the case of chiral secondary benzylic substrates. (Figure presented.).

Ipso- borylation of aryl ethers via Ni-Catalyzed C-OMe Cleavage

A Ni-catalyzed ipso-borylation of aryl ethers via C(sp2)-OMe and C(sp3)-OMe cleavage is described. The transformation is characterized by its wide substrate scope under mild conditions and an exquisite divergence in site selectivity that can be easily switched by selecting the appropriate boron reagent.

Nickel-catalyzed reductive and borylative cleavage of aromatic carbon-nitrogen bonds in N-aryl amides and carbamates

The nickel-catalyzed reaction of N-aryl amides with hydroborane or diboron reagents resulted in the formation of the corresponding reduction or borylation products, respectively. Mechanistic studies revealed that these reactions proceeded via the activation of the C(aryl)-N bonds of simple, electronically neutral substrates and did not require the presence of an ortho directing group.