62853-52-5

Basic information

• Product Name: methyl 6-deoxy-2,3-di-O-methyl-α-D-glucopyranoside
• Synonyms: methyl 6-deoxy-2,3-di-O-methyl-α-D-glucopyranoside
• CAS NO: 62853-52-5
• Molecular Weight: 206.239
• Mol File: 62853-52-5.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: methyl 6-deoxy-2,3-di-O-methyl-α-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 6-deoxy-2,3-di-O-methyl-α-D-glucopyranoside(62853-52-5)
• EPA Substance Registry System: methyl 6-deoxy-2,3-di-O-methyl-α-D-glucopyranoside(62853-52-5)

Safety Data

• Hazardous Substances Data: 62853-52-5(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 112693-26-2 C₃₇H₆₂O₁₇ 
• 922733-34-4 C₂₃H₄₃NO₈Si 

Relevant articles and documents

Stereoselective mannich-like reactions of ester enolates generated on sugar templates: A novel access to a key intermediate for 1β-methylcarbapenem synthesis

The Mannich-like reactions of the enolates generated from 2,3-di-O-protected 6-deoxy-4-O-propionyl-α-D-glucopyranosides with (3R,4R)-4-acetoxy-3-((R)-1-(t-butyldimethylsilyloxy)ethyl ]azetidin-2-one were investigated. The corresponding 2,3-di-O-methyl derivative provided the Mannich adduct in good to excellent stereoselectivity. From the major adduct, the azetidin-2-one incorporating an α-methyl acetic acid side chain at the C-4 position with ?-configuration was obtained by alkaline hydrolysis. This product, (3S,4S)-3-[(R)-1-(t-butyldimethylsilyloxy)ethyl 1-4-1(R)-1-carboxyethylJazetidin-2-one, is a useful intermediate for the 1 ?-methylcarbapenem synthesis.

GLYCOSIDES OF MARINE INVERTEBRATES. XV. A NEW TRITERPENE GLYCOSIDE - HOLOTHURIN A1 - FROM CARIBBEAN HOLOTHURIANS OF THE FAMILY HOLOTHURIIDAE

A glycoside, holothurin A1 has been isolated from the polar glycosidic fractions of the holothurians H. floridana and H. grisea.The complete structure of the glycoside has been established; it is: 3β-3)-O-β-D-glucopyranosyl-(1->4)-O-β-D-quinovopyranosyl-(1->2)-(4-sulfato-β-D-xylopyranosyl)oxy>holosta-9(11)-ene-12α,17α,22ξ-triol.Details of the IR and 1H and 13C NMR spectra of the compounds obtained are given.

Legume saponin of Gleditsia japonica Miquel. II. Desmonoterpenyl glycoside of echinocystic acid

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