62859-26-1

Basic information

• Product Name: (1R,4α)-1,7,7-Trimethyl-3-(1-hydroxy-2,2,2-trifluoroethylidene)bicyclo[2.2.1]heptane-2-one
• Synonyms: (1R,4S)-3-(2,2,2-Trifluoro-1-hydroxyethylidene)-1,7,7-trimethylbicyclo[2.2.1]heptane-2-one;(1R,4α)-1,7,7-Trimethyl-3-(1-hydroxy-2,2,2-trifluoroethylidene)bicyclo[2.2.1]heptane-2-one;(1R,4α)-1β,7,7-Trimethyl-3-(2,2,2-trifluoro-1-hydroxyethylidene)bicyclo[2.2.1]heptan-2-one
• CAS NO: 62859-26-1
• Molecular Formula: C12H15F3O2
• Molecular Weight: 248.24
• Mol File: 62859-26-1.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 293.1°C at 760 mmHg
• Flash Point: 131°C
• Appearance: /
• Density: 1.278g/cm³
• Vapor Pressure: 0.000187mmHg at 25°C
• Refractive Index: 1.48
• CAS DataBase Reference: (1R,4α)-1,7,7-Trimethyl-3-(1-hydroxy-2,2,2-trifluoroethylidene)bicyclo[2.2.1]heptane-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,4α)-1,7,7-Trimethyl-3-(1-hydroxy-2,2,2-trifluoroethylidene)bicyclo[2.2.1]heptane-2-one(62859-26-1)
• EPA Substance Registry System: (1R,4α)-1,7,7-Trimethyl-3-(1-hydroxy-2,2,2-trifluoroethylidene)bicyclo[2.2.1]heptane-2-one(62859-26-1)

Safety Data

• Hazardous Substances Data: 62859-26-1(Hazardous Substances Data)

Usage

InChI:InChI=1/C12H15F3O2/c1-10(2)6-4-5-11(10,3)8(16)7(6)9(17)12(13,14)15/h6,17H,4-5H2,1-3H3/b9-7+/t6-,11+/m1/s1

Upstream product

• 383-63-1 ethyl trifluoroacetate, 
• 464-49-3 (1R,4R)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one 

Relevant articles and documents

Oxidation of Alkenes and Sulfides with Transition Metal Catalysts

Alkenes and sulfides were oxidized with transition-metal catalysts.The oxidant sources include molecular dioxygen, air and iodosylbenzene.The metal ions Mn(III), Fe(III), Co(II) and Ni(II) were used.The catalysts 1-18 of 1,3-dioxo-, β-ketoimine- or salen-types were prepared and their efficacy was examined. 1,2-Dihydronaphthalene is most efficiently epoxidized with O2/Me2CHCHO or PhIO in the presence of Mn(III)-salen catalysts.The Ni(II)-, Co(II)- and Fe(III)-catalysts of either β-ketoimine- or salen-types are useful for epoxidation of styrene, (E)-stilbene and (E)-benzalacetone in the O2/Me2CHCHO system; these epoxidations are stereospecific without formation of corresponding diastereomeric epoxides.Oxidation of methyl p-totyl sulfide with O2/Me2CHCHO is facilitated by the 1,3-dioxo-catalyst Co(II)-1.Monooxidation is achieved with Me2CHCHO in equimolar proportions to give the corresponding sulfoxide, whereas overoxidation is realized with excess Me2CHCHO to give the sulfone.These epoxidation and sulfide oxidations all occur at 25 deg C and are complete in less than a day.Key Words: Oxidation; Transition metals; Alkenes; Sulfides; 1,3-Diketone; β-Ketoimine; Salen.