62879-80-5Relevant articles and documents
Catalytic reductive dehydration of tertiary amides to enamines under hydrosilylation conditions
Volkov, Alexey,Tinnis, Fredrik,Adolfsson, Hans
supporting information, p. 680 - 683 (2014/03/21)
Tertiary amides are efficiently reduced to their corresponding enamines under hydrosilylation conditions, using a transition-metal-free catalytic protocol based on t-BuOK (5 mol %) and (MeO)3SiH or (EtO) 3SiH as the reducing agent. The enamines were formed with high selectivity in good-to-excellent yields.