62980-80-7

Basic information

• Product Name: tricarbonyl(η5-diphenylphosphinocyclopentadienyl)manganese
• Synonyms: tricarbonyl(η5-diphenylphosphinocyclopentadienyl)manganese
• CAS NO: 62980-80-7
• Molecular Weight: 388.241
• Mol File: 62980-80-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: tricarbonyl(η5-diphenylphosphinocyclopentadienyl)manganese(CAS DataBase Reference)
• NIST Chemistry Reference: tricarbonyl(η5-diphenylphosphinocyclopentadienyl)manganese(62980-80-7)
• EPA Substance Registry System: tricarbonyl(η5-diphenylphosphinocyclopentadienyl)manganese(62980-80-7)

Safety Data

• Hazardous Substances Data: 62980-80-7(Hazardous Substances Data)

Upstream product

• 14516-54-2 bromopentacarbonylmanganese(I) 
• 85320-10-1 (diphenylphosphino)cyclopentadienylthallium 
• 12079-65-1 cymantrene 
• 1079-66-9 chloro-diphenylphosphine 

Downstream Products

• 111489-27-1 (C₆H₆)Cr(CO)2(C₆H₅)2PC₅H₄Mn(CO)3 
• 78143-09-6 C₅H₃(P(C₆H₅)2)CHOMn(CO)3 
• 78142-25-3 C₅H₃(P(C₆H₅)2)2Mn(CO)3 
• 790224-58-7 (η2-[70]-fullerene)bis(diphenylphosphinocymantrene)palladium(0) 
• 502157-91-7 (η2-[60]-fullerene)bis(diphenylphosphinocymantrene)palladium(0) 
• 790224-58-7 η2-C70Pd(cymanthrenyldiphenylphosphine)2 

Relevant articles and documents

THE ORIENTATION OF SUBSTITUTION IN METALLATION OF DIMETHYLAMINOMETHYL-, HYDROXYMETHYL- AND DIPHENYLPHOSPHIONO-CYMANTRENES

Dimethylaminomethyl- and hydroxymethyl-cymantrenes, when treated with n-butyllithium, are selectively metallated in the 2(5) position of the Cp ringand are converted into 1,2-disubstituted derivatives of cymantrene by subsequent treatment with electrophilic reagents.Similar reactions in the case of diphenylphosphinocymantrene result in a selective preparation of 1,3-disubstituted derivatives.The metallation orientation is established by chemical methods and NMR-LIS (lanthanide-induced shift) techniques.A full assignment of signals in the PMR and 13C NMR spectra of the studied monosubstituted cymantrene derivatives has been effected.