62992-33-0Relevant articles and documents
Triethylsiloxymethyl-N,N-dimethylamine, Et3SiOCH2NMe2: A Dimethylaminomethylation (Mannich) Reagent for O–H, S–H, P–H and Aromatic C–H Systems
Gonzalez, Paulina E.,Sharma, Hemant K.,Chakrabarty, Sanchita,Metta-Maga?a, Alejandro,Pannell, Keith H.
, p. 5610 - 5616 (2017/10/13)
Triethylsiloxymethylamine, Et3SiOCH2NMe2, readily synthesized in high yield by the hydrosilylation reaction between Et3SiH and DMF, is an excellent (N,N-dimethylamino)methyl transfer agent to a representative range of aliphatic alcohols, thiols, and Ph2PH (E–H) materials. The reactions are almost instantaneous at room temperature in inert solvents and require no activating agents to produce E–CH2NMe2 products in high yields and illustrate the title compound as an excellent addition to the family of organic reagents. For aromatic alcohols, electrophilic substitution of the aromatic ring occurs in high yield. Crystal structures of new materials such as the cholestero–CH2NMe2 derivative, 2–4-[bis(N,N-dimethylamino)methyl]-1-naphthol, and the phosphine oxide derived from Ph2PCH2NMe2 are reported.
A New Convenient Synthesis of Dialkyl(methylene)ammonium Chloride
Rochin, C.,Babot, O.,Dunogues, J.,Duboudin, F.
, p. 228 - 229 (2007/10/02)
A new, convenient synthesis of dialkyl(methylene)ammonium chloride is proposed from gem-aminoethers and methyltrichlorosilane, a by-product of the industrial methylchlorosilane synthesis.
CIDNP STUDY OF THE PHOTOCLEAVAGE OF BENZYL DERIVATIVES
Gardini, G. P.,Charlton, J. L.,Bargon, J.
, p. 987 - 990 (2007/10/02)
Evidence of the mechanistic pathways involved in the acetone sensitized homolytic photocleavage of benzyltrialkylammonium salts and other benzyl derivatives is obtained by CIDNP.
