62999-70-6Relevant articles and documents
THE USE OF PHOSPHONODITHIOFORMATES FOR THE SYNTHESIS OF KETENE DITHIOACETALS
Bulpin, Andrew,Masson, Serge,Sene, Aboubacary
, p. 3415 - 3418 (2007/10/02)
Phosphonodithioformates 1 undergo thiophilic addition with both organolithium and Grignard reagents to give metallated dithioacetals of formyl-phosphonates 2, available for protonation, alkylation or use in Wittig-Horner reactions.Oxidation of 1 by meta-c
ZUR SYNTHESE VON BIS-ALKLYLMERCAPTO-METHANPHOSPHONSAEUREDIALKYLESTERN
Gross, Hans,Keitel, Iris,Costisella, Burkhard,Mikolajczyk, Marian,Midura, Wanda
, p. 257 - 262 (2007/10/02)
To find a simple and reproducible synthesis of bis-alkylmercaptomethane phosphonates 1 several methods had been examined.The reaction of chloro-dialkylmercaptomethanes 3 with trialkylphosphite (Method A) and the reaction of diethylmethanphosphonate 8 with mercaptanes (Method F) proved to be the best methods.