63017-14-1

Basic information

• Product Name: 2-Butanone, 3-chloro-3-fluoro-
• CAS NO: 63017-14-1
• Molecular Formula: C4H6ClFO
• Molecular Weight: 124.542
• Mol File: 63017-14-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-Butanone, 3-chloro-3-fluoro-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Butanone, 3-chloro-3-fluoro-(63017-14-1)
• EPA Substance Registry System: 2-Butanone, 3-chloro-3-fluoro-(63017-14-1)

Safety Data

• Hazardous Substances Data: 63017-14-1(Hazardous Substances Data)

Upstream product

• 55949-61-6 trans-2,3-Dichloro-2,3-dimethyloxirane 

Relevant articles and documents

Halogen Epoxides, 3. Reactions of 2-Chloro- and 2,3-Dichlorooxiranes with Silver Tetrafluoroborate: Synthesis of α-Fluorinated Carbonyl Compounds

Reactions of chlorinated oxiranes with silver tetrafluoroborate in ether have been investigated.Substituted-2-chlorooxiranes (4a - e) afforded the corresponding α-fluorocarbonyl compounds (7a - e) as major products and the isomeric α-chlorocarbonyl compounds (8a - e) as minor products.Substituted 2,3-dichlorooxiranes (10, 14, 20, 24) yielded the isomeric α,α-dichloroketones (13, 19, 22, 26b, 29b) as well as the corresponding α-chloro-α-fluoroketones (12, 17, 21, 26a, 29a) and α,β-unsaturated α-chloroketones (18, 23, 27, 30).The course of the reaction was rationalized.Similar reaction with α-chloroketones and with α,α-dichloroketones succeeded only at substrates (8b, 35) in which the chlorine substituents were in benzylic positions.