63023-79-0

Basic information

• Product Name: Methanone, (3,4-dihydro-1-isoquinolinyl)phenyl-
• CAS NO: 63023-79-0
• Molecular Formula: C16H13NO
• Molecular Weight: 235.285
• Mol File: 63023-79-0.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Methanone, (3,4-dihydro-1-isoquinolinyl)phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Methanone, (3,4-dihydro-1-isoquinolinyl)phenyl-(63023-79-0)
• EPA Substance Registry System: Methanone, (3,4-dihydro-1-isoquinolinyl)phenyl-(63023-79-0)

Safety Data

• Hazardous Substances Data: 63023-79-0(Hazardous Substances Data)

Upstream product

• 64-04-0 phenethylamine 
• 13665-04-8 2,2-dibromoacetophenone 
• 5460-60-6 N-phenethyl-2-phenylacetamide 
• 402717-66-2 1-benzoyl-N-4-methylbenzenesulfonyl-1,2,3,4-tetrahydroisoquinoline 
• 75397-65-8 C₁₆H₁₃⁽²⁾H₂N 
• 24853-83-6 1-benzyl-3,4-dihydro-isoquinoline 

Relevant articles and documents

EVIDENCE FOR A CHARGE-TRANSFER MECHANISM IN THE PHOTO-OXYGENATION OF AN ENAMINE

Evidence for a charge-transfer mechanism in the photo-oxygenation of the enamine form of 1-benzyl-3,4-dihydroisoquinolines is presented.Substituent effects, normalized to constant enamine concentration, fit best a mechanism involving the formation of a ra

Desulfonylation of N-sulfonyl tetrahydroisoquinoline derivatives by potassium fluoride on alumina under microwave irradiation: Selective synthesis of 3,4-dihydroisoquinolines and isoquinolines

In a solvent-free system, the microwave irradiation of mixtures of N-sulfonyl tetrahydroisoquinolines and 37% potassium fluoride supported on alumina selectively furnished 3,4-dihydroisoquinolines or isoquinolines, depending upon the reaction time.

Synthesis and Photo-oxygenation of Some Substituted 1-Benzyl-3,4-dihydroisoquinolines. Mechanism of Enamine Photo-oxygenation

The synthesis of a series of substituted 1-benzyl-3,4-dihydroisoquinolines by Bischler-Napieralski cyclization is described.Competitive methylene blue sensitized photo-oxygenation experiments allowed the determination of relative rates of photo-oxygenation of 1-benzyl-3,4-dihydroisoquinolines.Substituents were shown to affect both the equilibrium concentration of the tautomeric enamine and the overall photo-oxygenation rate.After correcting for differences in enamine concentration, the relative rate data provided a diagnostic probe of the reaction mechanism, which involves transfer of charge in the rate-limiting step.