63133-61-9

Basic information

• Product Name: 3-Cyclopentene-1,1-dicarboxylic acid, 3,4-bis[(phenylthio)methyl]-, dimethyl ester
• CAS NO: 63133-61-9
• Molecular Formula: C23H24O4S2
• Molecular Weight: 428.573
• Mol File: 63133-61-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-Cyclopentene-1,1-dicarboxylic acid, 3,4-bis[(phenylthio)methyl]-, dimethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Cyclopentene-1,1-dicarboxylic acid, 3,4-bis[(phenylthio)methyl]-, dimethyl ester(63133-61-9)
• EPA Substance Registry System: 3-Cyclopentene-1,1-dicarboxylic acid, 3,4-bis[(phenylthio)methyl]-, dimethyl ester(63133-61-9)

Safety Data

• Hazardous Substances Data: 63133-61-9(Hazardous Substances Data)

Upstream product

• 63104-44-9 dimethyl 2,2-di(prop-2-ynyl)malonate 
• 108-98-5 thiophenol 

Relevant articles and documents

Radical cyclization in heterocycle synthesis. 12. Sulfanyl radical addition-addition-cyclization (SRAAC) of unbranched diynes and its application to the synthesis of A-ring fragment of 1 α,25-dihydroxyvitamin d3

Sulfanyl radical addition-addition-cyclization (SRAAC) of unbranched diynes proceeded smoothly to give cyclized exo-olefins, while the sulfanyl radical addition-cyclization-addition (SRACA) of diynes having a quaternary carbon gave cyclized endo-olefins. This method was successfully applied to the synthesis of A-ring fragment of 1 α,25-dihydroxyvitamin D3.