63163-54-2Relevant articles and documents
Kinetics and mechanism of monomolecular heterolysis of commercial organohalogen compounds: XLI. Solvent effect on the rate of 3-methyl-3-chloro-1- butene solvolysis. Correlation analysis of solvation effects and role of solvent nucleophilicity
Ponomarev,Zaliznyi,Dvorko
, p. 1430 - 1436 (2005)
The kinetics of 3-methyl-3-chloro-1-butene solvolysis at 25°C in MeOH, EtOH, BuOH, i-BuOH, PentOH, 2-PrOH, 2-BuOH, HexOH, OctOH, t-BuOH, t-PentOH, cyclohexanol, and allyl alcohol was studied by the verdazyl method; v = k[C 5H9Cl], SN1 + E1 mechanism. The reaction rate shows a satisfactory correlation with the parameter of the solvent ionizing power E T and is independent of the solvent nucleophilicity. 2005 Pleiades Publishing, Inc.