6318-49-6

Basic information

• Product Name: 1-ethenylcyclohexyl acetate
• CAS NO: 6318-49-6
• Molecular Formula: C₁₀H₁₆O₂
• Molecular Weight: 168.2328
• Mol File: 6318-49-6.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 201.3°C at 760 mmHg
• Flash Point: 66°C
• Density: 0.96g/cm³
• Vapor Pressure: 0.311mmHg at 25°C
• Refractive Index: 1.462
• CAS DataBase Reference: 1-ethenylcyclohexyl acetate(CAS DataBase Reference)
• NIST Chemistry Reference: 1-ethenylcyclohexyl acetate(6318-49-6)
• EPA Substance Registry System: 1-ethenylcyclohexyl acetate(6318-49-6)

Safety Data

• Hazardous Substances Data: 6318-49-6(Hazardous Substances Data)

Usage

Physical state

Colorless liquid

Odor

Sweet, fruity

Uses

Flavoring agent, fragrance ingredient in food and cosmetics industries

Synthesis

Precursor in the synthesis of various organic compounds

Health hazards

Potential irritant to skin, eyes, and respiratory system

Precautions

Safety measures should be taken when handling

Ingestion

May be hazardous if ingested

Storage and usage

Must be stored and used in accordance with proper safety guidelines

Upstream product

• 5240-32-4 1-acetoxy-1-ethynyl cyclohexane 
• 1940-19-8 1-vinylcyclohexanol 
• 108-24-7 acetic anhydride 
• 108-94-1 cyclohexanone 
• 78-27-3 1-Ethynylcyclohexan-1-ol 

Downstream Products

• 56037-77-5 1-(acetyloxy)cyclohexanecarboxaldehyde 
• 6282-51-5 1-Acetoxycyclohexancarbonsaeure 
• 118633-53-7 1-(1-acetoxy-cyclohexyl)-2-bromo-ethanol 
• 29538-98-5 1-(4-Cyclohexylidenbutyl)-cyclohexylacetat 
• 18559-89-2 3-cyclohexylidene-propionic acid ethyl ester 
• 79753-67-6 (2-cyclohexylidene-ethyl)dimethyl(phenyl)silane 
• 71442-92-7 1-<(2-hydroxy)ethyl>-1-vinylcyclohexane 
• 4441-58-1 4-Cyclohexylidenebutan-1-ol 
• 63922-76-9 (2-cyclohexylideneethyl)trimethylsilane 
• 177483-66-8 <2-(cyclohexylidene)ethyl>(diethylamino)diphenylsilane 
• 4442-90-4 2-cyclohexylideneethan-1-amine 
• 215033-08-2 (Z)-(2-Cyclohexylideneethyl)(2-methylbut-2-enyl)diphenylsilane 
• 55591-26-9 2-(cyclohexylidene)ethanol acetate 
• 932-89-8 2-cyclohexylidene ethanol 

Relevant articles and documents

ETHERS AND ESTERS OF 1-SUBSTITUTED CYCLOALKANOLS FOR USE AS AROMA CHEMICALS

The present invention relates to the use of an ether or an ester of a 1 -substituted cycloalkanol or of mixtures of two or more ethers or esters of 1 -substituted cycloalkanols or of a stereoisomer thereof or of a mixture of two or more stereoisomers thereof as aroma chemicals; to the use thereof for modifying the scent character of a fragranced composition; to an aroma chemical composition containing an ether or an ester of a 1 -substituted cycloalkanol or of mixtures of two or more ethers or esters of 1 -substituted cycloalkanols or of a stereoisomer thereof or of a mixture of two or more stereoisomers thereof; and to a method of preparing a fragranced composition or for modifying the scent character of a fragranced composition. The invention further relates to specific ethers or esters of 1 -substituted cycloalkanols.

Practical synthesis of allylic silanes from allylic esters and carbamates by stereoselective copper-catalyzed allylic substitution reactions

The first copper-catalyzed allylic substitution reactions of allylic acetates and carbamates employing a bis(triorganosilyl)zinc reagent are reported. This novel procedure avoids the use of stoichiometric amounts of copper salts which are usually mandatory with this chemistry. Application of this methodology to standard model substrates substantiates a high diastereoselectivity for the double bond geometry (E:Z) as well as the relative configuration (syn:anti).