631921-67-0Relevant articles and documents
Steric Course of Deprotonation/Substitution of Chelating/Dipole-Stabilizing-Group-Substituted α-Amino- and α-Oxynitriles
Sasaki, Michiko,Shimabara, Rumiko,Takegawa, Tomo,Kotomori, Yuri,Otani, Yuko,Ohwada, Tomohiko
, p. 4128 - 4134 (2018/08/22)
The stereochemical course of electrophilic substitutions of α-nitrile metallocarbanions was investigated through the deprotonation of enantioenriched α-amino- and α-oxynitriles bearing a carbamoyl or methoxycarbonyl group in the presence of an electrophil