63361-61-5

Basic information

• Product Name: 3-n-butyloxypyridine
• Synonyms: 3-n-butyloxypyridine
• CAS NO: 63361-61-5
• Molecular Formula: C9H13NO
• Molecular Weight: 151
• Mol File: 63361-61-5.mol
• Article Data: 7

Chemical Properties

• Boiling Point: 107-108 °C(Press: 13 Torr)
• Appearance: /
• Density: 0.968±0.06 g/cm3(Predicted)
• PKA: 4.77±0.10(Predicted)
• CAS DataBase Reference: 3-n-butyloxypyridine(CAS DataBase Reference)
• NIST Chemistry Reference: 3-n-butyloxypyridine(63361-61-5)
• EPA Substance Registry System: 3-n-butyloxypyridine(63361-61-5)

Safety Data

• Hazardous Substances Data: 63361-61-5(Hazardous Substances Data)

Upstream product

• 109-00-2 3-HYDROXYPYRIDINE 
• 109-65-9 1-bromo-butane 
• 1120-90-7 3-iodopyridine 
• 71-36-3 butan-1-ol 
• 626-55-1 3-Bromopyridine 
• 626-60-8 3-Chloropyridine 

Relevant articles and documents

MCM-41-immobilized 1,10-phenanthroline-copper(i) complex: A highly efficient and recyclable catalyst for the coupling of aryl iodides with aliphatic alcohols

A heterogeneous C-O coupling reaction between aryl iodides and aliphatic alcohols was achieved in neat alcohol or toluene at 110 °C in the presence of 10 mol% of the MCM-41-immobilized 1,10-phenanthroline-copper(i) complex [MCM-41-1,10-phen-CuI] with Cs2CO3 as a base, yielding a variety of aryl alkyl ethers in good to excellent yields. The new heterogeneous copper catalyst can easily be prepared by a simple procedure from commercially available and inexpensive reagents, and recovered by filtration of the reaction solution and recycled at least 8 times without significant loss of activity.

Alkoxylation reactions of aryl halides catalyzed by magnetic copper ferrite

Copper ferrite (CuFe2O4), which is easy-made, air-stable, low cost, easy separable, and regenerable, was applied as catalyst in an efficient method for C-O coupling reactions between various kinds of unactivated alkyl alcohols and aryl halides. This method only adopts 2.5% mol CuFe2O4 catalyst and selectively proceeds to C-O bond formation even sensitive substituents exist in the system.

A general and efficient catalyst for palladium-catalyzed C-O coupling reactions of aryl halides with primary alcohols

An efficient procedure for palladium-catalyzed coupling reactions of (hetero)aryl bromides and chlorides with primary aliphatic alcohols has been developed. Key to the success is the synthesis and exploitation of the novel bulky di-1-adamantyl-substituted bipyrazolylphosphine ligand L6. Reaction of aryl halides including activated, nonactivated, and (hetero)aryl bromides as well as aryl chlorides with primary alcohols gave the corresponding alkyl aryl ethers in high yield. Noteworthy, functionalizations of primary alcohols in the presence of secondary and tertiary alcohols proceed with excellent regioselectivity.