6337-27-5

Basic information

• Product Name: 2-cyano-3-furan-2-yl-N-(1-phenylethyl)prop-2-enamide
• CAS NO: 6337-27-5
• Molecular Formula: C₁₄H₁₂O₃
• Molecular Weight: 266.2946
• Mol File: 6337-27-5.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 487.9°C at 760 mmHg
• Flash Point: 248.9°C
• Density: 1.192g/cm³
• Vapor Pressure: 1.14E-09mmHg at 25°C
• Refractive Index: 1.598
• CAS DataBase Reference: 2-cyano-3-furan-2-yl-N-(1-phenylethyl)prop-2-enamide(CAS DataBase Reference)
• NIST Chemistry Reference: 2-cyano-3-furan-2-yl-N-(1-phenylethyl)prop-2-enamide(6337-27-5)
• EPA Substance Registry System: 2-cyano-3-furan-2-yl-N-(1-phenylethyl)prop-2-enamide(6337-27-5)

Safety Data

• Hazardous Substances Data: 6337-27-5(Hazardous Substances Data)

Upstream product

• 108-31-6 maleic anhydride 
• 2288-18-8 2-phenyl-1,3-butadiene 
• 71-43-2 benzene 
• 7306-12-9 1-acetoxy-3-phenyl-but-3-ene 
• 84736-61-8 (+/-)-(3-hydroxy-3-phenyl-butyl)-acetate 
• 7133-68-8 3-phenylbutane-1,3-diol 
• 98-83-9 isopropenylbenzene 
• 6051-52-1 2-phenylbut-3-en-2-ol 
• 6249-81-6 3-phenyl-but-3-en-2-ol 
• 767-99-7 2-phenylbut-2-ene 
• 1565-75-9 2-phenyl-2-butanol 
• 860687-81-6 (1,2-dibromo-1-methyl-propyl)-benzene 
• 17993-97-4 1-phenyl-2-(trimethylsilyl)ethanol 
• 13735-78-9 1-phenyl-2-(trimethylsilyl)ethanone 

Relevant articles and documents

A ruthenium-based catalytic system with switchable selectivity between cyclotrimerization and enyne metathesis/Diels-Alder reactions of terminal alkynes

In this study, we report a practical catalytic system, [RuCl 2(p-cymene)]2/IPr (IPr: 1,3-bis(2,6 diisopropylphenyl) imidazol-2-ylidene), that can switch between cyclotrimerization and cross enyne metathesis. The cyclotrimerization reaction of phenylacetylene catalyzed by [RuCl2(p-cymene)]2 can be switched to enyne metathesis by the introduction of a sterically hindered N-heterocyclic carbene. The 1,3-diene formed during this reaction reacts with dienophiles to form the Diels-Alder adduct. A practical one-pot synthesis method, utilizing enyne metathesis/Diels-Alder reactions, was used to construct cyclic compounds in an efficient manner.

A SILICON DIRECTED DIENE SYNTHESIS

A convenient method for the conversion of a series of aldehydes into substituted dienes is reported which uses silicon as a control element.