63499-93-4Relevant articles and documents
Catalytic transformation of esters of 1,2-azido alcohols into α-amido ketones
Kim, Yongjin,Pak, Han Kyu,Rhee, Young Ho,Park, Jaiwook
, p. 6549 - 6552 (2016/06/01)
The esters of 1,2-azido alcohols were transformed into α-amido ketones without external oxidants through the Ru-catalyzed formation of N-H imines with the liberation of N2 followed by intramolecular migration of the acyl moiety. A wide range of α-amido ketones were obtained, and one-pot transformation into the corresponding oxazoles (or a thiazole) was demonstrated.
NOUVELLE METHODE DE PREPARATION DE CETONES, ESTER ET NITRILE BENZYLIQUES α-FLUORES OU α,α-DIFLUORES
Laurent, E.,Marquet, B.,Tardivel, R.,Thiebault, H.
, p. 2359 - 2362 (2007/10/02)
By anodic oxidation in CH3CN/Et3N, 3HF benzylic ketones, ester and nitrile yield specifically corresponding monofluoro or difluoro compounds.The reaction proceeds through an α-carbonyl or an α-cyano carbocation.