63509-96-6Relevant articles and documents
Carbenoid chain reactions: Substitutions by organolithium compounds at unactivated 1-chloro-1-alkenes
Knorr, Rudolf,Pires, Claudio,Behringer, Claudia,Menke, Thomas,Freudenreich, Johannes,Rossmann, Eva C.,Boehrer, Petra
, p. 14845 - 14853 (2008/02/09)
The deceptively simple "cross-coupling" reactions Alk 2C=CA-Cl + RLi → Alk2C=CA-R + LiCl (A = H, D, or Cl) occur via an alkylidenecarbenoid chain mechanism in three steps without a transition metal catalyst. In the initiating step 1,