635310-43-9Relevant articles and documents
Switchable Synthesis of Z-Homoallylic Boronates and E-Allylic Boronates by Enantioselective Copper-Catalyzed 1,6-Boration
Luo, Yunfei,Wales, Steven M.,Korkis, Stamatis E.,Roy, Iain D.,Lewis, William,Lam, Hon Wai
, p. 8315 - 8319 (2018)
The enantioselective Cu-catalyzed 1,6-boration of (E,E)-α,β,γ,δ-unsaturated ketones is described, which gives homoallylic boronates with high enantiomeric purity and unexpectedly high Z-selectivity. By changing the solvent, the outcome can be altered to give E-allylic boronates.
