63542-04-1Relevant articles and documents
Phosphorylation with monomeric metaphosphates
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, (2008/06/13)
Solid substrates with free hydroxyl groups are phosphorylated by thermolysing a solution of phosphoramidate of the formula STR1 in the presence of the substrate, whereby metaphosphate is generated which phosphorylates the substrate.
SOLVOLYSIS OF DIPHENYL AMIDOPHOSPHATES IN AQUEOUS ALCOHOLIC MEDIA
Kasparek, Frantisek,Mollin, Jiri
, p. 386 - 396 (2007/10/02)
Influence of substituent on the reaction rate of the alkali-catalyzed solvolysis of the studied compounds set has been followed.The activation entropy has also been determined.The reaction products have been identified, and their concentration ratio has been determined.The reaction selectivity is mostly influenced by sterical effects in the substrate molecule.The results obtained agree with the SN2 mechanism.