637337-44-1Relevant articles and documents
Benzyl N-[(benzyloxy)methyl]carbamate: An improved aminomethylation electrophile for the synthesis of (benzyloxy)carbonyl (Cbz)-protected chiral β2-amino acids
Brocklehurst, Cara E.,Furegati, Markus,Mueller-Hartwieg, J. Constanze D.,Ossola, Flavio,La Vecchia, Luigi
experimental part, p. 314 - 323 (2010/05/14)
α-Aminomethylation of (R)-DIOZ-alkylated (DIOZ=4-isopropyl-5,5- diphenyloxazolidin-2-one) substrates is a key step in the asymmetric synthesis of β2-amino acids, but it is unfortunately often accompanied by formation of transcarbamation by-prod