63898-24-8Relevant articles and documents
Synthesis of cis- and trans-Artemidins
Chatterjea, J. N.,Bhakta, C.,Mukherjee, Sanat K.
, p. 992 - 993 (2007/10/02)
Cis- and trans-artemidins (4) and (5) have been synthesised from 3-butanoylisocoumarin (1).Compound (1) on sodium borohydride reduction affords the alcohol (2) which is converted into the mesylate (3).The mesylate (3) on dehydration using 1,5-diazabicycloundecene-5 at room temperature in benzene furnishes a mixture of 4 and 5, which are separated by column chromatography over silica gel.