64019-57-4

Basic information

• Product Name: TRIS(2-BENZIMIDAZOLYLMETHYL)AMINE)
• Synonyms: TRIS(2-BENZIMIDAZOLYLMETHYL)AMINE);tris(2-benzimidazoylmethyl)amine;Tris((1H-benzo[d]imidazol-2-yl)methyl)amine;(BimH)3;N,N-Bis(1H-benzimidazol-2-ylmethyl)-1H-benzimidazole-2-methanamine;Tris(2-benzimidazolylmethyl)amine 97%;1-(1H-benzimidazol-2-yl)-N,N-bis(1H-benzimidazol-2-ylmethyl)methanamine
• CAS NO: 64019-57-4
• Molecular Formula: C₂₄H₂₁N₇
• Molecular Weight: 407.48
• Product Categories: Click Catalyst and LigandsChemical Synthesis;Catalysis and Inorganic Chemistry;Chemical Ligation;Click Chemistry;Other Ligands
• Mol File: 64019-57-4.mol
• Article Data: 17

Chemical Properties

• Melting Point: 277-281 °C(lit.)
• Boiling Point: 821.176°C at 760 mmHg
• Flash Point: 450.431°C
• Appearance: /
• Density: 1.433g/cm³
• Vapor Pressure: 0mmHg at 25°C
• Refractive Index: 1.824
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• PKA: 10.37±0.10(Predicted)
• CAS DataBase Reference: TRIS(2-BENZIMIDAZOLYLMETHYL)AMINE)(CAS DataBase Reference)
• NIST Chemistry Reference: TRIS(2-BENZIMIDAZOLYLMETHYL)AMINE)(64019-57-4)
• EPA Substance Registry System: TRIS(2-BENZIMIDAZOLYLMETHYL)AMINE)(64019-57-4)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-37/39
• WGK Germany: 3
• Hazardous Substances Data: 64019-57-4(Hazardous Substances Data)

Usage

Description

TRIS(2-BENZIMIDAZOLYLMETHYL)AMINE), also known as tris(2-benzimidazolylmethyl)amine, is an organic compound with a unique structure that features three benzimidazolylmethyl groups attached to an amine core. TRIS(2-BENZIMIDAZOLYLMETHYL)AMINE) is known for its versatile chemical properties and potential applications in various fields due to its ability to form complexes and interact with different molecules.

Uses

Used in Pharmaceutical Industry:
TRIS(2-BENZIMIDAZOLYLMETHYL)AMINE) is used as a reactant for the synthesis of carbonic anhydrase models. Carbonic anhydrase is an enzyme that plays a crucial role in various physiological processes, including respiration, pH regulation, and ion transport. By synthesizing models of this enzyme, researchers can study its structure, function, and potential as a target for therapeutic intervention in various diseases.
Used in Chemical Research and Material Science:
TRIS(2-BENZIMIDAZOLYLMETHYL)AMINE) is used as a reactant for the synthesis of porous lanthanide tris(benzimidazolylmethyl)amine nitrato frameworks. These frameworks are of interest in the field of material science due to their unique properties, such as high surface area, porosity, and potential for ion exchange. They can be used in various applications, including gas storage, catalysis, and separation processes.

InChI:InChI=1/C24H21N7/c1-2-8-17-16(7-1)25-22(26-17)13-31(14-23-27-18-9-3-4-10-19(18)28-23)15-24-29-20-11-5-6-12-21(20)30-24/h1-12H,13-15H2,(H,25,26)(H,27,28)(H,29,30)

Upstream product

• 139-13-9 nitrilotriacetic acid 
• 95-54-5 1,2-diamino-benzene 
• 92206-38-7 ammonia triacetic acid 

Downstream Products

• 82137-72-2 tris(N-methylbenzimidazol-2-ylmethyl)amine 
• 159665-22-2 [(N(CH₂(C₇H₅N₂))3)ZnOCO(C₆H₄OH)]⁽¹⁺⁾*ClO₄^(1-) = [(N(CH₂(C₇H₅N₂))3)ZnOCO(C₆H₄OH)](ClO₄) 
• 318498-39-4 [(tris(benzimidazolylmethyl)amine)Zn((p-Br-benzyl-O)2POOPO₂(p-Br-benzyl-O))]ClO₄ 
• 318498-50-9 [(tris(benzimidazolylmethyl)amine)Zn((p-t-Bu-phenyl-OPO₂)2O)] 
• 64014-50-2 (Co(tris(2-benzimidazolylmethyl)amine)(NCS))BPh₄ 
• 207611-77-6 Mn(C₂₄H₂₁N₇)(C₇H₅O₃)⁽¹⁺⁾*ClO₄^(1-) = [Mn(C₂₄H₂₁N₇)(C₇H₅O₃)]ClO₄ 
• 204253-23-6 [Zn(N(CH₂CHN₂C₆H₄)3)SCH₂C₆H₅]⁽¹⁺⁾*ClO₄^(1-)=[Zn(N(CH₂CHN₂C₆H₄)3)SCH₂C₆H₅]ClO₄ 
• 204253-21-4 [Zn(N(CH₂CHN₂C₆H₄)3)SC₆H₅]⁽¹⁺⁾*B(C₆H₅)4^(1-)=[Zn(N(CH₂CHN₂C₆H₄)3)SC₆H₅][B(C₆H₅)4] 
• 205387-77-5 (benzoato-O)[tris((2-benzimidazol-N⁽³⁾)methyl)amine-N]zinc(II) tetrafluoroborate 

Relevant articles and documents

tris-(Benzimidazol-2-yl-methyl)-amine as a versatile building block in Ru(II) polypyridyl chemistry

tris-(Benzimidazol-2-yl-methyl)-amine, H3ntb, was prepared and used in the synthesis of dinuclear Ru(II) polypyridyl and polynuclear Ru(II)-Co(III) complexes of the type [Ru2(H2ntb) (bpy)4]3+, [Rusub

Cis-Dichloro[tris(2-benzimidazolylmethyl)amine]iron(III) chloride ethanol dihydrate: Hydrogen bonding changing the arrangement of tapes built from π-π and C - H...πctions

The title compound, [FeCl2(C24H21N 7)]Cl·C2H5OH·2H2O, comprises an [FeCl2(C24H21N7)] + cation, a Cl- anion, an ethanol molecule and two water molecules. The cations are linked by π-π and C - H...π interactions into one-dimensional tapes, and hydrogen bonding between the cations, Cl- anions, and ethanol and water molecules links these tapes into a three-dimensional network.

Efficient 4f-5d emission processes of Ce3+complexes with benzimidazole-based tetradentate ligands

A Ce3+complex with tetradentate ligands based on benzimidazole moieties was synthesized. The photochemical properties of the Ce3+complex were studied via absorption and emission spectra and emission quantum yield measurements. The effective values of the molar absorption coefficient and the emission quantum yield were estimated to be 890 dm3mol-1cm-1and 0.58, respectively; these values are relatively large compared to those of common rare-earth metal complexes that exhibit 4f-4f emissions.

A binuclear ag(I) complex based on a tripodal ligand tris(2- benzimidazolylmethyl)amine: Synthesis and characterization

A new binuclear complex [Ag2(ntb)2](NO 3)2·(CH3OH) 1.5·(CH3CN)0.5 based on a tripodal ligand ntb (ntb = tris(2-benzimidazolylmethyl)amine) has been synthesized and structurally characterized by X-ray single crystal diffractometry. In the structure of the complex each center Ag(I) ion is coordinated by two N atoms from two benzimidazole arm of one ntb ligand and one N atoms from one benzimidazole arm of the other in a trigonal coordinated geometry, resulting in the construction of a binuclear complex. The complex units are further linked into a 1-D chain by hydrogen bonds. The emission spectrum of the complex has been investigated and shows a red-shift of the emission peak compared to the ligand and the existence of ligand-to-metal charge transfer process (emission peak at 468.2 nm). Cyclic voltammogram of the complex indicates a pair of quasi-reversible redox couple, corresponding to the Ag+/Ag electrochemical process. Graphical Abstract: In the structure of the complex each center Ag(I) ion is coordinated by two N atoms from two benzimidazole arm of one ntb ligand and one N atoms from one benzimidazole arm of the other in a trigonal coordinated geometry, resulting in the construction of a binuclear complex.[Figure not available: see fulltext.]

METAL COMPLEXES FOR PROMOTING GROWTH IN A PHOTOSYNTHETIC ORGANISM

A method of promoting growth in a photosynthetic organism comprising treating the photosynthetic organism with a metal complex or a precursor thereof, wherein the metal complex comprises a metal selected from the group consisting of zinc (Zn), cobalt (Co), copper (Cu), nickel (Ni) and iron (Fe), and a ligand, which is a bidentate or tridentate ligand. Metal complexes and their ligands are also described.

A Highly Selective and Robust Co(II)-Based Homogeneous Catalyst for Reduction of CO2 to CO in CH3CN/H2O Solution Driven by Visible Light

Visible-light driven reduction of CO2 into chemical fuels has attracted enormous interest in the production of sustainable energy and reversal of the global warming trend. The main challenge in this field is the development of efficient, selective, and economic photocatalysts. Herein, we report a Co(II)-based homogeneous catalyst, [Co(NTB)CH3CN](ClO4)2 (1, NTB = tris(benzimidazolyl-2-methyl)amine), which shows high selectivity and stability for the catalytic reduction of CO2 to CO in a water-containing system driven by visible light, with turnover number (TON) and turnover frequency (TOF) values of 1179 and 0.032 s-1, respectively, and selectivity to CO of 97%. The high catalytic activity of 1 for photochemical CO2-to-CO conversion is supported by the results of electrochemical investigations and DFT calculations.