64065-24-3Relevant articles and documents
α-C-H Alkylation of Methyl Sulfides with Alkenes by a Scandium Catalyst
Luo, Yong,Ma, Yuanhong,Hou, Zhaomin
supporting information, p. 114 - 117 (2018/01/17)
The C - H addition of sulfides to alkenes is an atom-efficient route for the functionalization and modification of sulfide compounds through C - C bond formation, but this transformation is highly challenging. We report here the regioselective α-C(sp3) - H addition of a wide range of methyl sulfides to a variety of olefins and dienes by a half-sandwich scandium catalyst. This protocol provides a unique route for the synthesis of diverse sulfide derivatives through C - C bond formation at a sulfur-adjacent carbon atom in a 100% atom efficient fashion.