64101-66-2

Basic information

• Product Name: Ethanone, 1-[4-[(phenylsulfonyl)oxy]phenyl]-
• CAS NO: 64101-66-2
• Molecular Formula: C14H12O4S
• Molecular Weight: 276.313
• Mol File: 64101-66-2.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Ethanone, 1-[4-[(phenylsulfonyl)oxy]phenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 1-[4-[(phenylsulfonyl)oxy]phenyl]-(64101-66-2)
• EPA Substance Registry System: Ethanone, 1-[4-[(phenylsulfonyl)oxy]phenyl]-(64101-66-2)

Safety Data

• Hazardous Substances Data: 64101-66-2(Hazardous Substances Data)

Upstream product

• 791830-69-8 C₁₄H₁₄O₃S 
• 98-09-9 benzenesulfonyl chloride 
• 99-93-4 4-Hydroxyacetophenone 

Downstream Products

• 99-93-4 4-Hydroxyacetophenone 
• 1429416-51-2 triphenyl-(4-(benzenesulfoxy)benzoyl)-2’-methylenephosphorane 
• 1429416-53-4 (5S,2E)-3-(4’-benzenesulfoxyphenyl)ethynyl-5-(tert-butyldimethyl)silyloxy-1,7-di(4’-(benzenesulfoxy))phenylheptanone 
• 1429416-52-3 (5S,2E)-5-(tert-butyldimethyl)silyloxy-1,7-di(4’-(benzenesulfoxy))phenylhept-2-en-1-one 
• 1429416-50-1 2-bromo-4'-benzenesulfoxyacetophenone 
• 515-46-8 Ethyl benzenesulfonate 
• 92-91-1 biphenyl-4-acetaldehyde 
• 10537-63-0 1-(4-vinylphenyl)ethanone 

Relevant articles and documents

Site-Specific Oxidation of (sp3)C-C(sp3)/H Bonds by NaNO2/HCl

A site-specific oxidation of (sp3)C-C(sp3) and (sp3)C-H bonds in aryl alkanes by the use of NaNO2/HCl was explored. The method is chemical-oxidant-free, transition-metal-free, uses water as the solvent, and proceeds under mild conditions, making it valuable and attractive to synthetic organic chemistry.

Comparative Study of the Limitations and Challenges in Atom-Transfer C-H Oxidations

A comparative study is disclosed that seeks to highlight the current limitations and challenges that exist in the field of atom-transfer C-H oxidations. State-of-the-art methods are benchmarked in order to showcase clear differences and similarities. A novel Mn-mediated method for C-H oxidation is disclosed that serves as a rapid and simple method for aliphatic C-H hydroxylation. Finally, two methods that allow for C-H oxidation in the presence of pyridine-containing substrates are studied, something that is rare in the field but of great interest to the chemical community.

Total synthesis of (-)-blepharocalyxin D and analogues

An efficient strategy for the total synthesis of (-)-blepharocalyxin D and an analogue is described. The key step involves an acid-mediated cascade process in which reaction of methyl 3,3-dimethoxypropanoate with γ,δ- unsaturated alcohols possessing diastereotopic styrenyl groups gives trans-fused bicyclic lactones with the creation of two rings and four stereocenters in one pot.