64126-56-3Relevant articles and documents
Palladium-catalyzed direct arylation of indoles with cyclohexanones
Chen, Shanping,Liao, Yunfeng,Zhao, Feng,Qi, Hongrui,Liu, Saiwen,Deng, Guo-Jun
supporting information, p. 1618 - 1621 (2014/04/17)
A novel palladium catalyzed approach to 3-arylindoles was developed from indoles and cyclohexanones. Various cyclohexanones acted as aryl sources via an alkylation and dehydrogenation sequence using molecular oxygen as the hydrogen acceptor. This method showed good regioselectivity and afforded 3-arylindoles as the sole products.
Palladium-catalyzed intermolecular alkenylation of indoles by solvent-controlled regioselective C-H functionalization
Grimster, Neil P.,Gauntlett, Carolyn,Godfrey, Christopher R. A.,Gaunt, Matthew J.
, p. 3125 - 3129 (2007/10/03)
(Chemical Equation Presented) Either the C2- or the C3-substituted product can be obtained with the same palladium(II) catalyst in an oxidative intermolecular alkenylation of indoles. A variety of conditions can be used for derivatization at the 3-positio