6415-58-3

Basic information

• Product Name: 2,3-diphenyl-2-cyclopropene-1-carbonyl chloride
• Synonyms: 2,3-diphenyl-2-cyclopropene-1-carbonyl chloride
• CAS NO: 6415-58-3
• Molecular Weight: 254.716
• Mol File: 6415-58-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2,3-diphenyl-2-cyclopropene-1-carbonyl chloride(CAS DataBase Reference)
• NIST Chemistry Reference: 2,3-diphenyl-2-cyclopropene-1-carbonyl chloride(6415-58-3)
• EPA Substance Registry System: 2,3-diphenyl-2-cyclopropene-1-carbonyl chloride(6415-58-3)

Safety Data

• Hazardous Substances Data: 6415-58-3(Hazardous Substances Data)

Upstream product

• 17825-58-0 2,3-diphenylcycloprop-2-enecarboxylic acid 
• 501-65-5 diphenyl acetylene 
• 7382-06-1 ethyl 2,3-diphenylcycloprop-2-enecarboxylate 

Downstream Products

• 114611-40-4 2-butynylene di(1,2-diphenylcyclopropene-3-carboxylate) 
• 130561-99-8 6-tosyloxy-2,4-hexadiynyl 1,2-diphenylcyclopropane-3-carboxylate 
• 130562-01-5 22-hydroxy-10,12-docosadiynyl 1,2-diphenylcyclopropene-3-carboxylate 
• 130562-03-7 10,12-docosadiyn-1,22-ylene di(1,2-diphenylcyclopropene-3-carboxylate) 
• 3763-36-8 2,3-diphenylcycloprop-2-ene-1-carbaldehyde 
• 6415-73-2 1,2-diphenyl-3-hydroxymethyl-1-cyclopropene 
• 6415-70-9 2,3-Diphenyl-2-cyclopropen-1-carboxamid 
• 79643-31-5 ((2,3-diphenyl-2-cyclopropen-1-yl)carbonyl)pentacarbonylrhenium 
• 69302-82-5 (η-cyclopentadienyl)((2,3-diphenyl-2-cyclopropen-1-yl)carbonyl)dicarbonyliron 
• 82495-39-4 ((2,3-diphenyl-2-cyclopropen-1-yl)carbonyl)pentacarbonylmanganese 
• 15041-50-6 tetracobaltdodecacarbonyl 
• 80673-37-6 1-(2,3-Diphenyl-2-cyclopropen-1-yl)-2,2-diiodethanon 
• 80673-36-5 2,2-Dibrom-1-(2,3-diphenyl-2-cyclopropen-1-yl)ethanon 
• 80673-34-3 2,2-Dichlor-1-(2,3-diphenyl-2-cyclopropen-1-yl)ethanon 

Relevant articles and documents

Trans N-Methyl-N-[2-(1-pyrrolidinyl)cyclohexyl] cycloprop-2-ene-1-carboxamides: Novel lipophilic kappa opioid agonists

The synthesis and kappa opioid agonist activities of some lipophilic analogues of the kappa opioid agonist U-50488 incorporating motifs bearing two aromatic rings in place of the 3,4-dichlorophenyl group are described. Trans 2,3-diphenyl-N-methyl-N[2-(1-pyrrolidinyl)cyclohexyl]-2-cyclopropene-1 -carboxamide, 7, is a potent kappa opioid agonist. A diphenylcyclopropene analogue of CI-977, trans 2,3-diphenyl-N-methyl-N-[7-(1-pyrrolidinyl)-1-oxaspiro[4.5]dec-8-yl]-2 -cyclopropene-1-carboxamide, 13, is a highly lipophilic chemically novel potent selective kappa opioid agonist.

Small Rings, 33. Attempts to Synthesize Diphenyltetrahedrane

Carbene 7, formed on photochemical or thermal excitation of (2,3-diphenyl-2-cyclopropen-1-yl)diazomethane (6i), splits mostly into two acetylenes 8 and 9 instead of undergoing an intramolecular cycloaddition.Photolysis of the Masamune ketone 16 depending on the reaction conditions gives either p-terphenyl or a mixture of the two cyclooctatetraens 18 and 19.The intermediate formation of tetrahedrane 10 would fit into the mechanistic picture of this fragmentation.