643013-46-1

Basic information

• Product Name: Phosphonic acid, (5-chloro-1,1-difluoropentyl)-, diethyl ester
• CAS NO: 643013-46-1
• Molecular Formula: C9H18ClF2O3P
• Mol File: 643013-46-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Phosphonic acid, (5-chloro-1,1-difluoropentyl)-, diethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Phosphonic acid, (5-chloro-1,1-difluoropentyl)-, diethyl ester(643013-46-1)
• EPA Substance Registry System: Phosphonic acid, (5-chloro-1,1-difluoropentyl)-, diethyl ester(643013-46-1)

Safety Data

• Hazardous Substances Data: 643013-46-1(Hazardous Substances Data)

Upstream product

• 6940-78-9 4-chlorobutyl bromide 
• 94993-99-4 diethyl difluoromethylphosphonate lithium salt 

Relevant articles and documents

First synthesis of S,S-dialkyl difluorophosphonodithioates and difluorophosphonotrithioates

Several dialkyl difluoromethylphosphonodithioates and difluoromethylphosphonotrithioates have been prepared from difluoromethylphosphonyl dichloride and two equivalents of alkanethiols under basic conditions. Treatment of these species with LDA at low temperatures mainly resulted in decomposition, and to the low-yield isolation of difluorophosphinates or phosphine oxides, thus reflecting the lability of the P-S bond. The desired difluorophosphonodithioates and difluorophosphonotrithioates can be efficiently prepared by reversing the sequence of reactions.