64325-22-0

Basic information

• Product Name: Lithium, (1,2-difluoro-2-phenylethenyl)-
• CAS NO: 64325-22-0
• Molecular Formula: C8H5F2Li
• Molecular Weight: 146.066
• Mol File: 64325-22-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Lithium, (1,2-difluoro-2-phenylethenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Lithium, (1,2-difluoro-2-phenylethenyl)-(64325-22-0)
• EPA Substance Registry System: Lithium, (1,2-difluoro-2-phenylethenyl)-(64325-22-0)

Safety Data

• Hazardous Substances Data: 64325-22-0(Hazardous Substances Data)

Upstream product

• 89263-98-9 difluoro-1,2 phenyl-2 trimethylsilyl ethylene-(Z) 
• 395-00-6 (E/Z)-1-chloro-1,2-difluoro-2-phenylethene 
• 75-77-4 chloro-trimethyl-silane 
• 79-38-9 Chlorotrifluoroethylene 
• 591-51-5 phenyllithium 
• 85433-89-2 trans-α,β-difluorostyrene 

Downstream Products

• 1129-65-3 (hex-1-yn-1-yl)benzene 
• 128728-70-1 (E)-1,2-difluoro-1,4-diphenyl-3-butyn-1-ene 
• 370-84-3 phenylacetyl fluoride 
• 52776-46-2 1-fluoro-2-phenylacetylene 
• 70975-09-6 1,6-Diphenyl-1,3,5-perfluorhexatrien 
• 90786-33-7 difluoro-1,2 methyl-2 phenyl-1 ethylene-(E) 
• 19706-75-3 (Z)-β-iodo-α,β-difluorostyrene 
• 85433-92-7 C₈H₅ClF₂Mg 
• 85433-92-7 C₈H₅ClF₂Mg 
• 32741-39-2 1,8-Diphenyl-1,3,5,7-perfluoroctatetraen 

Relevant articles and documents

Low-temperature 19F NMR spectroscopy of 1-fluoro-1-lithioethenes - Stability, shifts and unexpected coupling constants

Half-lives and fluorine atom shifts of stabilized 1-fluoro-l-lithioethenes bearing hydrogen, fluorine, phenyl, and/or dimethylphenylsilyl groups in the β-positions have been determined by a low-temperature 19F NMR spectroscopy. Some 1-fluoro-1-lithioethenes displayed an exceptionally low value of the trans-3JFF coupling constant. Stereoselectivity of carbenoid formation, as well as an effect of configuration on the stability is discussed.