64482-94-6Relevant articles and documents
Poly(1,1-bis(dialkylamino)propan-1,3-diyl)s; Conformationally-controlled oligomers bearing electroactive groups
Alder, Roger W.,Hyland, Niall P.,Jeffery, John C.,Riis-Johannessen, Thomas,Riley, D. Jason
supporting information; experimental part, p. 2704 - 2715 (2009/09/07)
The design of polymers with repeating [C(NR2)2CH 2CH2] units which may simultaneously provide conformational control and contain repeating electroactive centres is discussed; (NR2)2 groups would be ideally provided by ortho-phenylenediamine derivatives, with 1,8-diaminonaphthalenes as alternatives. Oligomers containing 1,8-bis(methylamino)naphthalenes, up to the hexamer, were obtained by condensation of oligomers of CH3[COCH 2CH2]nCOCH3 with 1,8-bis(methylamino)naphthalene, but attempts to prepare related oligomers from 1,2-bis(alkylamino)benzenes were unsuccessful, as only terminal ketone groups could be converted to aminals. Evidence for a strong preference for all-anti conformations of the main chain in the naphthalenediamine oligomers is provided by ring current effects on 1H NMR shifts, and by X-ray structures, which also provide evidence of intercalation in the solid state. Electrochemical studies of these oligomers show irreversible oxidation of oligomers in solution, but oxidation of longer oligomers leads to the deposition of a reddish-pink insoluble material which shows two reversible oxidation waves. Possible interpretation of these results is discussed. The Royal Society of Chemistry 2009.
Process for preparing 2,3-dihydro-1,3-dialkyl-2,3-dialkyl perimidines and N,N-'-dialkyl-1,8-naphthalene diamines
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, (2008/06/13)
Processes for preparing 2,3-dihydro-1,3-dialkyl-2,2-dialkyl perimidines and N,N'-dialkyl-1,8-naphthalene diamines are disclosed. The 2,3-dihydro-1,3-dialkyl-2,2-dialkyl perimidines are prepared by alkylating 2,3-dihydro-2,2-dialkyl perimidines with an alkylating agent in a water miscible organic solvent at room temperature to 80° C. in the presence of water and an inorganic base. N,N'-dialkyl-1,8-naphthalene diamines are prepared by hydrolyzing the 2,3-dihydro-1,3-dialkyl-2,2-dialkyl perimidines with strong aqueous acid in an aqueous organic solvent and removing a ketone by-product and the aqueous organic solvent by codistillation.
Electronic Structure of Heterospirenes-PE Spectroscopic Investigations
Gleiter, Rolf,Uschmann, Joachim
, p. 370 - 380 (2007/10/02)
The synthesis of the heterospirenes 1-9 is described and their He I photoelectron (PE) spectra are recorded.The assignment of the first PE bands is based on a comparison with fragment molecules and on molecular orbital calculations using semiempirical methods (PPP, MINDO/3). in the case of 1, 2, 4, and 5 strong spirointeraction has been elucidated.For 3 the analysis of the spectrum is hampered due to the strong overlap of the bands while for 6 the nonplanarity brings about a reduction of spirointeractions.For 7-9 the interaction between both fragments could not be detected.